Citation: HAO Jin-Ming, LI Huan-Huan, LI Guang-Yue, CUI Guang-Hua. Two Dimensional Cadmium (Ⅱ) Coordination Polymer Constructed from Flexible Bis(triazole) Ligand:Synthesis, Structure and Fluorescence Property[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2450-2454. doi: 10.3969/j.issn.1001-4861.2013.00.361
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The new coordination polymer named, {[Cd(L)(HBTC)(H2O)]·H2O}n (L=1,2-bis(1,2,4-triazol-1-ylmethyl)benzene, H3BTC=1,3,5-benzenetricarboxylic acid) has been synthesized hydrothermally and characterized by elemental analysis, IR spectroscopy, thermogravimetric (TG) analysis and single-crystal X-ray diffraction analysis. The cadmium center is six coordinated with three OCOO-atoms from two different HBTC2- dianions and one water molecule locate in the equatorial positions, while apical sites are occupied by two Natoms from two distinct Lligands in a distorted octahedral geometry. The structural analysis shows that the complex possesses a two-dimensional 2D (4,4) layer structure, and displays a three-dimensional (3D) supramolecular structure via multiple intermolecular O-H…O hydrogen bonds. The fluorescence property of the complex also has been studied. CCDC: 917952.
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