Citation: ZHANG Yong, XIONG Qi-Jei, ZHANG Nan-Hai, CHEN Shi-Ming, ZHANG Ruo-Xuan, MA Zhi-Gang, CHEN Xue-Mei. Crystal Structure of Zinc(Ⅱ) Complex Containing Pyridine and Its Catalytic Activity of Hydrolysis of p-Nitrophenyl Phosphate[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(12): 2555-2560. doi: 10.3969/j.issn.1001-4861.2013.00.345 shu

Crystal Structure of Zinc(Ⅱ) Complex Containing Pyridine and Its Catalytic Activity of Hydrolysis of p-Nitrophenyl Phosphate

1.
1 School of Chemical and Materials Engineering, Hubei Polytechnic University, Huangshi, Hubei 435003, China;

Received Date: 26 February 2013
Available Online: 4 June 2013
Fund Project: 国家自然科学基金(No.51173060)资助项目。 (No.51173060)

A zinc(Ⅱ) complex [Zn₂(L) Cl₃]₂[ZnCl₄]·CH₃CN·CH₃OH·3H₂O (L=1,1,4,7,7-Pentakis (2-pyridyl-methyl) diethylenetriamine) has been synthesized and structurally characterized, and its catalytic activity was investigated by using p-nitrophenyl phosphate (PNPP) as the substrate. The results showed that one zinc(Ⅱ)) of the complex was coordinated in a distorted trigonal-bipyramidal geometry, and the coordination geometry around another zinc(Ⅱ) was distorted octahedron. Its catalytic hydrolysis of PNPP was consistent with Michaelis-Mentent model. Several kinetic parameters V_max, K_m and K_cat were examined under different conditions, and maximal catalytic activity of zinc(Ⅱ) complex was observed at a temperature of 30 ℃ and pH=8.0. CCDC: 921868.
- zinc(Ⅱ) complex;pyridine;crystal structure;catalytic activity
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沈阳化工大学材料科学与工程学院沈阳 110142