Citation: DU Xiu-Hong, CUI Jie-Hu. Hydrothermal Synthesis, Crystal Structure and Photochemical Properties of a Nickel(Ⅱ) Coordination Polymer Based on a Tripodal Flexible Carboxylate Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2445-2449. doi: 10.3969/j.issn.1001-4861.2013.00.341 shu

Hydrothermal Synthesis, Crystal Structure and Photochemical Properties of a Nickel(Ⅱ) Coordination Polymer Based on a Tripodal Flexible Carboxylate Ligand

DU Xiu-Hong ¹ ,
CUI Jie-Hu ²

1.
1 Henan Medical College for Staff and Workers, Zhengzhou 451191, China;

Received Date: 16 July 2012
Available Online: 21 February 2013
Fund Project: 国家自然科学基金(No.21101055)资助项目。 (No.21101055)

A coordination polymer {[Ni(H₂BCPBA)₂(H₂O)₄]}_n (1, H₃BCPBA=3,5-bi(4-carboxy-phenoxy)-benzoic acid) has been synthesized from H₃BCPBA by using hydrothermal method and structurally characterized by elemental analysis, IR spectrum, UV spectroscopy, TG and single-crystal X-ray diffraction. Single-crystal X-ray analysis reveals that the coordination polymer 1 is crystallized in the triclinic system, space group P1. The Ni(Ⅱ) ion is six-coordinated by two oxygen atoms from H₂BCPBA^- ligand and four oxygen atoms from water molecules, generating a octahedral coordination geometry. UV spectroscopy study reveals that the coordination polymer exhibits strong ultraviolet absorption in the solid state at room temperature. CCDC: 837882.
- hydrothermal synthesis;crystal structure;Ni(Ⅱ) coordination polymer;UV spectroscopy
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