Citation: TAI Xi-Shi, ZHAO Wen-Hua, LI Fa-Hui. Synthesis, Crystal Structure and Antitumor Activity of Ca(Ⅱ) Coordination Polymer Constructed by N-Benzenesulphonyl-L-phenylalanine[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2200-2204. doi: 10.3969/j.issn.1001-4861.2013.00.272
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Colourless crystals of 1Dcoordination polymer, [Ca(L)2(H2O)2(CH3CH2OH)]n (L=N-benzenesulphonyl-L-phenylalanine), were obtained by the reaction of calcium perchlorate and N-benzenesulphonyl-L-phenylalanine in the 95% CH3CH2OH solution, and characterized by elemental analysis, IRand X-ray single crystal diffraction analysis. The single-crystal X-ray analysis of the title complex reveals that each Ca(Ⅱ) atom is seven-coordinated in a distorted pentagonal bipyramid coordination environment by seven oxygen atoms from the N-benzenesulphonyl-L-phenylalanine ligand, the coordinated water molecule and the coordinated CH3CH2OH molecule, respectively. The molecular structure is 1D coordination polymer by the interaction of bridged carboxylato groups. The antitumor activity against SMMC-7721, A549, WiDr and P388 cancer cells of the Ca(Ⅱ) complex also was investigated. CCDC: 890991.
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