Citation: WANG Peng, XUE Zhao-Teng, MA Jing-Hong, KANG Yu-Hong, LI Rui-Feng. Zeolite LTA with Intracrystal Mesopores Constructed by Bond-Blocking Principle[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1777-1786. doi: 10.3969/j.issn.1001-4861.2013.00.269
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Zeolite LTA with intracrystal mesopores was built using four different organic functionized SiO2 as configuration units. The effects of the synthesis conditions, including that of the alkalinity, the Si/Al molar ratio of synthesis mixture and crystallization time, on the growth process of the mesostructured zeolite crystals were investigated. Phenylaminopropyl-trimethoxysilane is the best candidate to create intracrystal mesopores in zeolite LTA crystals. The growth process of the mesostructured zeolite crystals was studied. Mesoporous size of the zeolite LTA can be modulated by selecting different kinds of organosilanes. Within a certain range, the external surface area and the mesoporous volume increase with the increasing organic function degree of the silica source. The results confirm that the synthesis method by the bond-blocking principle is an effective route to prepare zeolite LTA with tunable intracrystalline mesopores.
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