Citation: LIANG Han, KANG Jing-Jing, GUO Qiong, ZHANG Qi, FEI Ri-Ling, GUO Zi-Dong, LI Lian-Zhi. Synthesis, Crystal Structure and Spectroscopic Characterization of Two Chiral Oxovanadium Complexes[VO(Naph-Leu)(OMe)(CH₃OH)] and[VO(Naph-Phe)(OMe)(CH₃OH)][J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1819-1824. doi: 10.3969/j.issn.1001-4861.2013.00.264 shu

Synthesis, Crystal Structure and Spectroscopic Characterization of Two Chiral Oxovanadium Complexes[VO(Naph-Leu)(OMe)(CH₃OH)] and[VO(Naph-Phe)(OMe)(CH₃OH)]

1.
School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252059, China

Received Date: 15 January 2013
Available Online: 29 March 2013
Fund Project: 聊城大学大学生科技文化创新基金(No.SF2012048和SRT11043HX2) (No.SF2012048和SRT11043HX2)山东省自然科学基金(No.Y2004B02)资助项目。 (No.Y2004B02)

Two new chiral oxovanadium complexes,[VO(Naph-Leu)(OMe)(CH₃OH)] (1) and[VO(Naph-Phe)(OMe)(CH₃OH)] (2), (Naph-Leu=Schiff base derived from 2-hydroxy-1-naphthaldehyde and L-leucine, Naph-Phe=Schiff base derived from 2-hydroxy-1-naphthaldehyde and L-phenylalanine), have been synthesized. Single crystal X-ray diffraction analysis showed that complex 1 crystallized in the orthorhombic crystal system, space group P2₁2₁2 with the cell parameters: a=0.946 80(8) nm, b=3.246 3(3) nm, c=0.662 37(5) nm, V=2.035 9(3) nm³, Z=4, F(000)=864, R₁=0.046 3, wR₂=0.112 7, S=1.076; and complex 2, crystallized in the monoclinic crystal system, space group P2₁ with the cell parameters: a=1.113 41(11) nm, b=0.724 09(6) nm, c=1.342 99(12) nm, V=1.047 95(16) nm³, Z=2, F(000)=464, R₁=0.035 8, wR₂=0.088 8, S=1.024. The IR, UV-Vis and circular dichroism (CD) spectra of the two complexes were measured and discussed. CCDC: 885240, 1; 897188, 2.
- chirality;oxovanadium complex;crystal structure;CD spectra
1. [1]
  [1] Vilter H. Phytochemistry, 1984,23:1387-1390
2. [2]
  [2] Robson R L, Eady R R, Richardson T H, et al. Nature, 1986, 322:388-390
3. [3]
  [3] Dubyak G R, Kleinzeller A. J. Biol. Chem., 1980,255(11): 5306-5312
4. [4]
  [4] Thompson K H, Orvig C. J. Inorg. Biochem., 2006,100:1925-1935
5. [5]
  [5] Heyliger C E, Tahiliani A G, McNeil J H. Science, 1985, 227:1474-1477
6. [6]
  [6] Shechter Y, Karlish S J. Nature, 1980,284:556-558
7. [7]
  [7] Thompson K H, McNeill J H, Orvig C. Chem. Rev., 1999, 99:2561-2572
8. [8]
  [8] HUANG Yu-Ting(黄玉婷), OUYANG Xing-Mei(欧阳兴梅), Okamura T, et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2005,21(10):1479-1482
9. [9]
  [9] Singh H L, Sharma M, Varshney A K. Synth. React. Inorg. Met-Org. Chem., 2000,30:445-456
10. [10]
  [10] Nath M, Pokharia S, Yadav R. Coord. Chem. Rev., 2001, 215:99-149
11. [11]
  [11] Narla R K, Dong Y, D'Cruz O J, et al. Clin. Cancer Res., 2000,6:1546-1456
12. [12]
  [12] Li L Z, Guo Z H, Zhang Q F, et al. Inorg. Chem. Commun., 2010,13(10):1166-1169
13. [13]
  [13] Bian L, Li L Z, Zhang Q F, et al. Trans. Met. Chem., 2012, 37:783-790
14. [14]
  [14] Xu T, Li L Z, Zhou S F, et al. J. Chem. Crystallogr., 2005, 35(4):263-267
15. [15]
  [15] LI Lian-Zhi(李连之), XU Tao(许涛), WANG Da-Qi(王大奇), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2004, 20(2):236-240
16. [16]
  [16] BIAN Lin(边琳), LI Lian-Zhi(李连之), ZHANG Qing-Fu(张庆富), et al. Acta Chim. Sinica(Huaxue Xuebao), 2011,69 (14):1661-1666
17. [17]
  [17] Sheldrick G M. SHELXTL 6.10, Bruker Analytical Instrum-entation, Madison, Wisconsin, USA, 2000.
18. [18]
  [18] Kawabe K, Tadokoro M, Hirotsu K, et al. Inorg. Chim. Acta, 2000,305:172-183
19. [19]
  [19] ZHAO Xiao-Jing(赵小菁), ZHANG Li-Ying(张丽影), JIN Li-Ming(金黎明), et al. Chinese J. Org. Chem.(Youji Huaxue Xuebao), 2011,31(9):1516-1521
20. [20]
  [20] HONG Yong(洪涌), XIAO Jing-Yi(肖静怡), CHEN Shi-Ping (陈世平), et al. Chinese J. Org. Chem.(Youji Huaxue Xuebao), 2008,28(8):1404-1409
21. [21]
  [21] LI Xiao-Li(李晓丽), RUAN Wen-Juan(阮文娟), NAN Jing (南晶), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2005,21(11):1655-1660
1. [1]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
2. [2]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
3. [3]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
4. [4]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
5. [5]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
6. [6]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
7. [7]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
8. [8]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
9. [9]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
10. [10]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
11. [11]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
12. [12]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
13. [13]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
14. [14]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
15. [15]
  Jinlong YAN , Weina WU , Yuan WANG . A simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1653-1660. doi: 10.11862/CJIC.20240154
16. [16]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
17. [17]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
18. [18]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
19. [19]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
20. [20]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(378)
HTML views(25)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Crystal Structure and Spectroscopic Characterization of Two Chiral Oxovanadium Complexes[VO(Naph-Leu)(OMe)(CH3OH)] and[VO(Naph-Phe)(OMe)(CH3OH)]

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis, Crystal Structure and Spectroscopic Characterization of Two Chiral Oxovanadium Complexes[VO(Naph-Leu)(OMe)(CH₃OH)] and[VO(Naph-Phe)(OMe)(CH₃OH)]