Citation: NIE Xiao-Li, HUO Yan-Ping, LU Tian-Hua, HU Sheng, YI Guo-Bin, YUAN Guo-Zan. Synthesis and Photophysics of Novel Zn Metal Complex Based on 2-Substituted-8-hydroxyquinoline with Trifluoromethylbenzene Group[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1805-1812. doi: 10.3969/j.issn.1001-4861.2013.00.254
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A novel 8-hydroxyquinoline derivative ligand containing trifluoromethylbenzene Group: (E)-2-[2-(2-trifluromethylphenyl)vinyl]-8-hydroxyquinoline(4) and its zinc complex(5) have been synthesized and identified by 1H NMR, FFIR, MS techniques and elemental analyses. The crystal structure of ligand 4 was determined by X-ray single crystal diffraction, and its network structure is special spiral. The aggregation behavior of Zn(AcO)2·2H2O and the ligand 4 in solvents was investigated by UV-Vis, fluorescence spectrum and 1H NMR spectra titration. Fluorescence emission results showed that the λmax of ligand 4 and complex 5 were 474 nm and 601 nm, respectively. The fluorescence lifetime of ligand 4 and complex 5 were investigated in the solid state, their values are 15.6 ms and 18.1 ms, respectively. CCDC: 910120.
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