Citation: ZHANG Dong-Teng, ZHU Ying-Ying, LUO Guang-Ming, CAI Hu. Synthesis and Characterization of Tert-butylimido Tetra-chloro Tantalum(Ⅴ) Anion Complex [IPrH]+[tBuN=TaCl4(py)]-[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 953-957. doi: 10.3969/j.issn.1001-4861.2013.00.162
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[IPrH]+[tBuN=TaCl4(py)]- (1) (IPr=1,3-bis(2,6-diisoproylphenyl)imidazol-2-ylidene) was obtained unexpe-ctedly by the reaction of tBuN=TaCl3(py)2 and IPr. Complex 1 was structurally characterized by NMR, IR, fluores-cence spectra, elemental analysis and single-crystal X-ray diffraction. The crystal structure of 1 shows that the Ta(Ⅴ) center is octahedrally coordinated by four chlorides and two nitrogen atoms from imido and pyridyl ligands, respectively. CCDC: 873803.
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