Citation: LI Cai-Yun, WANG Yong-Ming. Theoretical Analyses of Vacuum Ultraviolet Absorption Spectra of Ho3+ Doped in LiYF4 Crystal[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 735-738. doi: 10.3969/j.issn.1001-4861.2013.00.136
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Spectral terms and J-spectral multiplet of low-spin 4f95d configuration of Ho3+ were obtained with the method of ligand field theory. According to the selection rules for dipole transitions, the absorption spectra of Ho3+ doped in LiYF4 in vacuum ultraviolet region (120~160 nm) of the spectrum were theoretically interpreted by applying the crystal field model, and the four main bands were assigned to the spin-allowed transitions from the ground state (5I8) to J-spectral multiplet of low-spin 4f95d configuration of Ho3+ ion.
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