Citation: HU Wei-Ji, WU Xiao-Yong, LIU Jian-Feng, ZHAO Guo-Liang. Synthesis, Crystal Structure and Biological Activity of Lanthanum(Ⅲ) Coordination Polymer Constructed with p-Hydroxyphenylacetic Acid Anion[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 861-866. doi: 10.3969/j.issn.1001-4861.2013.00.134
-
A coordination polymer of {[La(HPAA)3(H2O)2]·2(bipy)·H2O}n (1) (HHPAA=p-hydroxyphenylacetic acid, bipy=4,4′-bipyridine) was synthesized and characterized by elemental analysis, IR and TG-DTG. Its crystal structure was determined by single crystal X-ray diffraction method. The complex crystallizes in triclinic with space group P1, cell parameters: a=0.910 52(2) nm, b=1.284 78(3) nm, c=1.958 69(4) nm, α=78.586 0(1)°, β=76.656 0(1)°, γ=73.097 0(1)°, cell volume: V=2.111 98(8) nm3, number of molecules inside the cell: Z=2, relative molecular mass: Mr=958.73. The La(Ⅲ) cation is coordination with oxygen atoms from p-hydroxyphenylacetic acid anions and water molecules, forming a distorted two-capped square antiprism coordination geometry. The adjacent La(Ⅲ) clusters linked by carboxylic groups are connected by HPAA- to form a 1D chain, and the bipyridine is uncoordinated to La(Ⅲ) center. Moreover, the interaction of complex with DNA was also studied by ethidium bromide (EB) fluorescence spectroscopy. CCDC: 900442.
-
-
[1]
[1] Sun X L, Wang Z J, Zang S Q, et al. Cryst. Growth Des., 2012,12(9):4431-4440
-
[2]
[2] Bradshaw D, Prior T J, Cussen E J, et al. J. Am. Chem. Soc., 2004,126(19):6106-6114
-
[3]
[3] Biswas R, Mukherjee S, Ghosh A, et al. Inorg. Chem., 2012, 51(15):8150-8160
-
[4]
[4] Mukherjee G, Singh P, Butcher R J, et al. Inorg. Chem., 2012,51(15):8128-8140
-
[5]
[5] HU Zong-Zhi(胡宗智), ZHAO Jun(赵君), LI Dong-Sheng(李 东升), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27:184-188
-
[6]
[6] Kim D W, Song X K, Yoon J H, et al. Cryst. Growth Des., 2012,12(8):4186-4193
-
[7]
[7] Li H J, Zhao B, Hou H W, et al. Cryst. Growth Des., 2012, 12(8):4170-4179
-
[8]
[8] Hu J S, Yao X Q, Xue Z L, et al. Cryst. Growth Des., 2012, 12(7):3426-3435
-
[9]
[9] Morris W, Cascio D, Yaghi M, et al. Inorg. Chem., 2012,51 (12):6643-6445
-
[10]
[10] LI Rong-Qing(李荣清), ZHANG Yu(张宇), ZHAO Zhen(赵 振), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(5):1025-1030
-
[11]
[11] WANG Hui(王慧), GAN Guo-Qing(甘国庆), QU Yang(瞿 阳), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(6):1217-1221
-
[12]
[12] Hudej R, Kljun J, Turel I, et al. Organometallics, 2012,31 (16):5867-5874
-
[13]
[13] Chen Z F, Shi Y F, Liang H, et al. Inorg. Chem., 2012,51 (4):1998-2009
-
[14]
[14] Xue L, Li G P, Jiang H, et al. Inorg. Chem., 2011,50(8): 3680-3690
-
[15]
[15] OU Zhi-Bin(区志镔), HUANG Shan-Hua(黄山华), LE Xue-Yi(乐学义). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(8):1580-1586
-
[16]
[16] Sheldrick G M. SHELXS 97, Program for the Solution of Crystal Structure, University of Göttingen, Gttingen, Germany, 1997.
-
[17]
[17] Sheldrick G M. SHELXS 97, Program for the Refinement of Crystal Structure, University of Göttingen, Gttingen, Germany, 1997.
-
[18]
[18] Hou H W, Wei Y L, Zhu Y, et al. Inorg. Chem., 2004,43(4): 1323-1327
-
[19]
[19] Delangle P, Husson C, Lebrun C, et al. Inorg. Chem., 2001, 40(13):2953-2962
-
[20]
[20] Lakowicz J R, Weber G. Biochem., 1973,12(21):4161-4170
-
[1]
-
-
[1]
Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two LnⅢ3 complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
-
[2]
Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
-
[3]
Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
-
[4]
Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb2 complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
-
[5]
Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
-
[6]
Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
-
[7]
Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
-
[8]
Chang Liu , Tao Wu , Lijiao Deng , Xuzi Li , Xin Fu , Shuzhen Liao , Wenjie Ma , Guoqiang Zou , Hai Yang . Programmed DNA walkers for biosensors. Chinese Chemical Letters, 2024, 35(9): 109307-. doi: 10.1016/j.cclet.2023.109307
-
[9]
Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
-
[10]
Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
-
[11]
Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
-
[12]
Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
-
[13]
Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
-
[14]
Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu2+. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
-
[15]
Shuyan ZHAO . Field-induced CoⅡ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
-
[16]
Jia-Li Xie , Tian-Jin Xie , Yu-Jie Luo , Kai Mao , Cheng-Zhi Huang , Yuan-Fang Li , Shu-Jun Zhen . Octopus-like DNA nanostructure coupled with graphene oxide enhanced fluorescence anisotropy for hepatitis B virus DNA detection. Chinese Chemical Letters, 2024, 35(6): 109137-. doi: 10.1016/j.cclet.2023.109137
-
[17]
Yang Qin , Jiangtian Li , Xuehao Zhang , Kaixuan Wan , Heao Zhang , Feiyang Huang , Limei Wang , Hongxun Wang , Longjie Li , Xianjin Xiao . Toeless and reversible DNA strand displacement based on Hoogsteen-bond triplex. Chinese Chemical Letters, 2024, 35(5): 108826-. doi: 10.1016/j.cclet.2023.108826
-
[18]
Xiaohong Wen , Mei Yang , Lie Li , Mingmin Huang , Wei Cui , Suping Li , Haiyan Chen , Chen Li , Qiuping Guo . Enzymatically controlled DNA tetrahedron nanoprobes for specific imaging of ATP in tumor. Chinese Chemical Letters, 2024, 35(8): 109291-. doi: 10.1016/j.cclet.2023.109291
-
[19]
Jingwen Zhao , Jianpu Tang , Zhen Cui , Limin Liu , Dayong Yang , Chi Yao . A DNA micro-complex containing polyaptamer for exosome separation and wound healing. Chinese Chemical Letters, 2024, 35(9): 109303-. doi: 10.1016/j.cclet.2023.109303
-
[20]
Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(221)
- HTML views(10)