Advanced Search

Citation: ZHOU Ya-Chong, ZHANG Sheng-Hui, OU Xue-Mei, ZHANG Xiao-Bin, ZHANG Xin. Thermal Decomposition Behavior and Deintercalation Kinetics of Kaolinite/ Benzamide Intercalation Complex[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 985-990. doi: 10.3969/j.issn.1001-4861.2013.00.112 shu

Thermal Decomposition Behavior and Deintercalation Kinetics of Kaolinite/ Benzamide Intercalation Complex

  • 1.

    School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China

  • Corresponding author: OU Xue-Mei, 
  • Received Date: 31 October 2012
    Available Online: 29 November 2012

    Fund Project: 中国矿业大学中央高校基本科研业务费专项资金(2012LWA02) 资助项目。 (2012LWA02)

  • The kaolinite/benzamide was prepared with a direct displacement intercalation method by using kaolinite/DMSO intercalation complex as an intermediate. The XRD and FTIR results show that benzamide has inserted into kaolinite and formed new hydrogen bonds with the inner surface of kaolinite. The thermal decomposition behavior of the complex was studied by TG and DSC. The TG and DSC results indicate that the decomposition process of the complex proceeds in two steps. The first step is deintercalation of the intercalated benzamide at 231 ℃ and the second step is dehydroxylation of kaolinite. For the first step, the kinetic triplet of the complex was calculated by the Modified Iterative Iso-conversional Procedure,Malek and Dollimore methods. The activation energy Ea is 75.4 kJ·mol-1, the range of pre-exponential factor A is 4.9×1010～8.8×1010 s-1. The optimized mechanism function is nth-order chemical reaction,the mechanism function is G(α)=[1-(1-α)1-n]/(1-n), f(α)=(1-α)n.
  • 加载中
    1. [1]

      [1] Matsumura A, Komori Y. Bull. Chem. Soc. Japan, 2001,74 (6):1153-1157

    2. [2]

      [2] WANG Lin-Jiang(王林江), WU Da-Qing(吴大清). Mater. Rev.(Cailiao Daobao), 2001,15(6):41-43

    3. [3]

      [3] Chen Z H, Huang C Y, Gong K C. Appl. PolySci. 2000,75 (6):796-801

    4. [4]

      [4] WANG Lin-Jiang(王林江), XIE Xiang-Li(谢襄漓), CHEN Nan-Chun(陈南春), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(5): 853-859

    5. [5]

      [5] CHEN Jie-YU(陈洁渝), AN Chun-Jie(严春杰), WAN Wei- Min(万为敏), et al. J. Chin. Cer. Soc.(Guisuanyan Xuebao), 2010,38(9):1837-1842

    6. [6]

      [6] WANG Lin-Jiang(王林江), WU Da-Qing(吴大清), YUAN Peng(袁鹏), et al. Chem. J. Chinese Universities.(Gaodeng Xuexiao Huaxue Xuebao), 2002,23(10):1945-1951

    7. [7]

      [7] CHEN Jie-Yu(陈洁渝), YAN Chun-Jie(严春杰). Acta Petrologica et Mineralogica(Yanshi Kuangwuxue Zazhi), 2003,22(1):99-102

    8. [8]

      [8] Cheng H F, Yang J, Frost R L, et al. J. Therm. Anal. Calorim., 2011,103:507-513

    9. [9]

      [9] QIN Fang-Fang(秦芳芳), HE Ming-Zhong(何明中), CUI Jing- Wei(崔景伟), et al. Chem. J. Chinese Universities(Gaodeng Xuexiao Huaxue Xuebao), 2007,28(12):2343-2348

    10. [10]

      [10] Xu Jian-Feng(徐剑锋), LIANG Yi-Ying(梁怡瑛), MA Ning (马宁), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(6):1121-1127

    11. [11]

      [11] ZHANG Sheng-Hui(张生辉), QIANG Ying-Huai(强颖怀), OU Xue-Mei(欧雪梅), et al. Spectroscopy and Spectral Analysis(Guangpuxue Yu Guangpu Fenxi), 2009,29(8):2067 -2070

    12. [12]

      [12] GardoIinski J E, Ramos L P, Wypych F. J. Colloid Interface Sci., 2000,221:284-287

    13. [13]

      [13] ZHANG Sheng-Hui(张生辉),YANG Wei(杨薇),XIA Hua (夏华). J. Chin. Cer. Soc.(Guisuanyan Xuebao), 2004,132:631

    14. [14]

      [14] HU Rong-Zu(胡荣祖), SHI Qi-Zhen(史启祯). Kinetics of Thermalanalysis (热分析动力学). Beijing: Science Press, 2001:149-167,241-243

    15. [15]

      [15] Sadtler Research Laboratories. Sadtler Standard Spectra. SRL: Philadelphia USA, 1980:9-10

    16. [16]

      [16] Malek J, Smrcka V. Thermochim. Acta, 1996,186(1):153 -169

    17. [17]

      [17] Malek J. Thermochim. Acta, 1992,200(1):257-267

    18. [18]

      [18] Malek J, Criado J M. Thermochim. Acta, 1994,236(1):187 -197

    19. [19]

      [19] Dollimore D, Tong P, Alexander K S. Thermochim. Acta, 1996,1:282-283

    20. [20]

      [20] CAO Xiu-Hua(曹秀华), WANG Lian-Shi(王炼石), ZHOU Yi-Yu(周奕雨). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2003,19(11):1237-1240

    21. [21]

      [21] ZHOU Jia(周佳), HE Ming-Zhong(何明中), ZHANG Ai Hua (张爱华), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(7):1279-1283

  • 加载中
    1. [1]

      Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO2-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067

    2. [2]

      Jing JIN , Zhuming GUO , Zhiyin XIAO , Xiujuan JIANG , Yi HE , Xiaoming LIU . Tuning the stability and cytotoxicity of fac-[Fe(CO)3I3]- anion by its counter ions: From aminiums to inorganic cations. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 991-1004. doi: 10.11862/CJIC.20230458

    3. [3]

      Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403

    4. [4]

      Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312

    5. [5]

      Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346

    6. [6]

      Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110

    7. [7]

      Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe3O4@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239

    8. [8]

      Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271

    9. [9]

      Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078

Get Citation
PDF
XML
Metrics
  • PDF Downloads(444)
  • Abstract views(477)
  • HTML views(17)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return