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Citation: JIA Yun-Jie, LI Ming-Lei, CUI Ji-Li, LIU Liang, WANG Run-Wei, YI Jian-Jun, XU Qing-Hong. 3D-Mesoporous Zirconium Phosphonate NTAZP: Synthesis and Formaldehyde Oxidation by Its Supported Fe3+ Catalyst[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 465-473. doi: 10.3969/j.issn.1001-4861.2013.00.078 shu

3D-Mesoporous Zirconium Phosphonate NTAZP: Synthesis and Formaldehyde Oxidation by Its Supported Fe3+ Catalyst

  • 1.

    1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China;

  • Received Date: 12 July 2012
    Available Online: 7 October 2012

    Fund Project: 国家自然科学基金(No.50602004) (No.50602004)

  • A new mesoporous zirconium phosphonate(NTAZP) was synthesized by using nitrilotris(methylene)-triphosphonic acid (ATMP) and zirconium dichloride oxide octahydrate. The as-prepared mesoporous materials were characterized by XRD, FTIR, TG-DTA and SEM techniques. Fe3+-based aminotrialkylene zirconium phosphonate catalyst was obtained by using NTAZP as the support and by treating the support with an aqueous solution of Fe(NO3)3. The results indicate that the structure and morphology of NTAZP are not changed after loading, and ferric species are mainly anchored on NTAZP via the coordinative interactions between Fe3+ and N atoms inside the mesoporous channel. The supported ferric species NTAZP (NTAZP-Fe3+) with a good thermal stability are highly catalytic active for formaldehyde oxidation in relatively mild reaction conditions. The Fe-based catalyst can prevent Fe3+ from dissolving into the water, and can be recycled to avoid secondary pollution. NTAZP-Fe3+ is a high-efficient and green catalyst in small-molecule aldehydes oxidation.
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