Citation: Cheng ZHANG, Zhen-Zhen HE, Wen-Li WANG, Wen-Jing GAO, Feng-Feng ZHANG, Xiao WANG, Long TANG, Er-Lin YUE, Ji-Jiang WANG, Xiang-Yang HOU. Design and synthesis of MOF-1 and Tb@MOF-1 as fluorescent probes for recognizing trace amounts of Cr₂O₇^2- and S₂O₈^2- ions[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(9): 1832-1840. doi: 10.11862/CJIC.2023.140 shu

Design and synthesis of MOF-1 and Tb@MOF-1 as fluorescent probes for recognizing trace amounts of Cr₂O₇^2- and S₂O₈^2- ions

Department of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China

Corresponding author: Xiao WANG, wx2248@126.com
Received Date: 19 December 2022
Revised Date: 20 June 2023

Figures(4)

A new fluorescent probe metal-organic framework (MOF) materials formulated as [Cd(PLIA)(TIB)]_n(MOF-1) was successfully obtained adopting 5-((4-pyridyl)methoxy)-isophthalic acid (H₂PLIA) and 1, 3, 5-tris(1-imidazolyl)-benzene (TIB). MOF-1 possesses 2D networks with an ideal 1D tunnel, and the 1D tunnel is spaced and driven by the flexible triangle PLIA^2- and rigid triangle TIB ligands. Employing the advantage of MOF-1 channel easy doping, efficient luminescent probe Tb@MOF-1 was also constructed using a coordinated post-synthetic modification strategy. MOF-1 and Tb@MOF-1 were fully characterized in detail, and the two probe materials have the same structural feature. The fluorescence recognition performance was investigated in detail, revealing a capability of MOF-1 for sensing Cr₂O₇^2-, Tb@MOF-1 for identifying S₂O₈^2- anion. Herein, the fabricated fluorescent probes exhibit fascinating features, such as fast response time, remarkable stability, excellent selectivity, and high sensitivity. The possible fluorescence recognition mechanism of Cr₂O₇^2- and S₂O₈^2- by MOF-1 and Tb@MOF-1 has been investigated, and the difference in the mechanism may be related to Tb³⁺ ion doping.
- metal-organic framework,
- synthesis,
- characterization,
- fluorescent probe,
- Cr₂O₇^2-,
- S₂O₈^2-
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通讯作者: 陈斌, bchen63@163.com

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Design and synthesis of MOF-1 and Tb@MOF-1 as fluorescent probes for recognizing trace amounts of Cr2O72- and S2O82- ions

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通讯作者: 陈斌, bchen63@163.com

Design and synthesis of MOF-1 and Tb@MOF-1 as fluorescent probes for recognizing trace amounts of Cr₂O₇^2- and S₂O₈^2- ions