Citation: Wan-Ting LIU, Xue YANG, Hong-Mei CHAI, Yi-Xia REN, Xiu-Fang HOU, Ji-Jiang WANG. Fluorescence sensing on nitrobenzene of two-dimensional Zn-coordination polymers based on tricarboxylate isomers[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(8): 1610-1618. doi: 10.11862/CJIC.2023.120 shu

Fluorescence sensing on nitrobenzene of two-dimensional Zn-coordination polymers based on tricarboxylate isomers

Shaanxi Key Laboratory of Chemical Reaction Engineering, Laboratory of New Energy and New Function Materials, College of Chemistry and Chemical Engineering, Yan′an University, Yan′an, Shaanxi 716000, China

Corresponding author: Yi-Xia REN, renyixia1@163.com
Received Date: 8 January 2023
Revised Date: 7 May 2023

Figures(5)

Two 2D zinc(Ⅱ) coordination polymers (CPs), named as [Zn₄(3-CIA)₂(OH)₂(3-bibz)₂] (1) and [Zn₂(4-CIA)(OH)(3-bibz)]·H₂O (2), where 3-H₃CIA=5-((3-carboxyphenoxy) methyl) isophthalic acid, 4-H₃CIA=5-((4-carboxyphenoxy) methyl) isophthalic acid, and 3-bibz=3-bis(imidazole-1-ylmethyl) benzene, have been prepared hydrothermally and characterized using techniques such as single crystal X-ray diffraction, IR, thermogravimetry, and powder X-ray diffraction. Structural analyses show 1 possesses 2D based on tetra-nuclear building units and 2 exhibits a 2D network from tri-nuclear units due to the different coordination fashions of organic ligands. The fluorescence sensing tests of CPs 1 and 2 on organic solvents showed that their fluorescence exhibited complete quenching by nitrobenzene in water, and the limits of detection were 0.248 and 0.309 μmol·L^-1, respectively. Through theoretical calculation, it is found that the sensing mechanism of the two CPs on nitrobenzene can be mainly attributed to the photoinduced electron transfer (PET) effect.
- zinc coordination polymer,
- crystal structure,
- nitrobenzene,
- fluorescence sensing
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