Citation: Ya-Bo ZHU, Cheng-Ye HUA, Ting-Ting XIE, Guang-Lan WANG, Pei-Zhong FENG. One-step synthesis of FeOOH/black phosphorus nano-composite: Synergistic achieving system's excellent oxygen evolution property[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(6): 1103-1112. doi: 10.11862/CJIC.2023.082 shu

One-step synthesis of FeOOH/black phosphorus nano-composite: Synergistic achieving system's excellent oxygen evolution property

School of Materials Science and Physics, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China

Corresponding author: Ya-Bo ZHU, zhuyabo@163.com
Received Date: 27 July 2022
Revised Date: 24 April 2023

Figures(9)

In the study, by hydrothermal method, FeOOH nano-materials were grown on the surface of black phosphorus (BP) nanosheets to prepare FeOOH/BP composite. As an oxygen evolution reaction (OER) electrocatalyst, its overpotential was only 191 mV at the current density of 20 mA·cm^-2, with a Tafel slope of 49.9 mV·dec^-1. After 1 000 cycles, its overpotential only increased by 3 mV, showing the best stability. FeOOH was loaded on the BP surface, which can hinder BP oxidation and enhance its carrier conduction ability. And the loaded nano-FeOOH had a small scale and a weak crystalline nature, which is conducive to enriching their active site and increasing the active area. The synergy of this binary system is the main reason for the OER performance improvement. By comparison, it was found that the active area of FeOOH/BP reached 26.9 mF·cm^-2, which was 2.3 times that of pure FeOOH (11.8 mF·cm^-2) and 1.6 times that of pure BP nanosheets (16.8 mF·cm^-2). The excellent activity of this composite material is not only attributed to the morphology change of FeOOH, which significantly expands its effective active area but also benefits from the encapsulated BP, which has better dispersion and stronger conductivity.
- black phosphorus,
- FeOOH,
- compound,
- oxygen evolution reaction,
- electrocatalytic mechanism
1. [1]
  LI J R, YIN Y L, ZHOU K H, WANG F, REN C B. Progress of oxygen generation technology by water electrolysis in space station[J]. Space Medicine & Medical Engineering, 2013,26(3):215-220. doi: 10.16289/j.cnki.1002-0837.2013.03.021
2. [2]
  Song S Z, Zhou J, Sun J, Zhang S Y, Lin X, Hu Z W, Hu J, Zhang L J, Wang J Q. Understanding the origin of high oxygen evolution reaction activity in the high Sr-doped perovskite[J]. Chin. J. Catal., 2020,41(4):592-597. doi: 10.1016/S1872-2067(19)63441-8
3. [3]
  Xu Y, Ren K L, Xu R. In situ formation of amorphous Fe-based bimetallic hydroxides from metal-organic frameworks as efficient oxygen evolution catalysts[J]. Chin. J. Catal., 2021,42(8):1370-1378. doi: 10.1016/S1872-2067(20)63741-X
4. [4]
  CHEN R X, ZHAI Z L, LI Z L, LU Y L, WANG D, WU Z C, LI Y P, HE G X, LI Y B. Preparation and OER properties of chromium-doped jarosite microspheres[J]. Nonferrous Metals (Extractive Metallurgy), 2022(5):77-85.
5. [5]
  Xu Q, Zhu Y B, Feng P Z, Lv K L, Xu H. In situ growth of porous carbon with adjustable morphology on black phosphorus nanosheets for boosting electrocatalytic H₂ and O₂ evolution[J]. New J. Chem., 2021,45(27):12203-12212. doi: 10.1039/D1NJ02185K
6. [6]
  Gao X Q, Liu X M, Yang S J, Zhang W. Black phosphorus incorporated cobalt oxide: Biomimetic channels for electrocatalytic water oxidation[J]. Chin. J. Catal., 2022,43(4):1123-1130. doi: 10.1016/S1872-2067(21)63937-2
7. [7]
  Liang T T, Lenus S, Ma F, Dai Z F. Interface and M³⁺/M²⁺ valence dual -engineering on nickel cobalt sulfoselenide/black phosphorus heterostructure for efficient water splitting electrocatalysis[J]. Energy Environ. Mater., 2022,6e12332.
8. [8]
  Ma P, Luo S, Ma J T. Vertically aligned FeOOH nanosheet arrays on alkali-treated nickel foam as highly efficient electrocatalyst for oxygen evolution reaction[J]. J. Colloid Interface Sci., 2020,574:241-250. doi: 10.1016/j.jcis.2020.04.058
9. [9]
  Feng J X, Xu H, Dong Y T, Ye S H, Tong Y X, Li G R. FeOOH/Co/FeOOH hybrid nanotube arrays as high -performance electrocatalysts for the oxygen evolution reaction[J]. Angew. Chem. Int. Ed., 2016,55(11):3694-3698. doi: 10.1002/anie.201511447
10. [10]
  Wang K, Du H F, Ai W, Huang W. Kinetically controlled, scalable synthesis of gamma-FeOOH nanosheet arrays on nickel foam toward efficient oxygen evolution: The key role of in - situ -generated γ-NiOOH[J]. Adv. Mater., 2021,33(11)e2005587. doi: 10.1002/adma.202005587
11. [11]
  Li H X, Zhou Q, Zhou H H, Huang Z Y, Jiao S Q, Kuang Y F. Biomimetic design of ultrathin edge-riched FeOOH@Carbon nanotubes as high-efficiency electrocatalysts for water splitting[J]. Appl. Catal. B - Environ., 2019,255117755. doi: 10.1016/j.apcatb.2019.117755
12. [12]
  Corcoran C J, Tavassol H, Rigsby M A, Bagus P S, Wieckowski A. Application of XPS to study electrocatalysts for fuel cells[J]. J. Power Sources, 2010,195(24):7856-7879. doi: 10.1016/j.jpowsour.2010.06.018
13. [13]
  Qiu C Y, He S Q, Wang Y, Wang Q X, Zhao C. Interfacial engineering FeOOH/CoO nanoneedle array for efficient overall water splitting driven by solar energy[J]. Chem.-Eur. J., 2020,26(18):4120-4127. doi: 10.1002/chem.201904352
14. [14]
  Lee J, Lee H, Lim B. Chemical transformation of iron alkoxide nanosheets to FeOOH nanoparticles for highly active and stable oxygen evolution electrocatalysts[J]. J. Ind. Eng. Chem., 2018,58:100-104. doi: 10.1016/j.jiec.2017.09.013
15. [15]
  Cheng J L, Shen B S, Song Y Y, Cheng Y L. FeOOH decorated CoP porous nanofiber for enhanced oxygen evolution activity[J]. Chem. Eng. J., 2022,428131130. doi: 10.1016/j.cej.2021.131130
16. [16]
  Shi F B, Geng Z B, Huang K K, Feng S H. Cobalt nanoparticles/black phosphorus nanosheets: An efficient catalyst for electrochemical oxygen evolution[J]. Adv. Sci., 2018,5(8)1800575. doi: 10.1002/advs.201800575
17. [17]
  Wang J H, Liu D N, Huang H, Yu X F. In-plane black phosphorus/dicobalt phosphide heterostructure for efficient electrocatalysis[J]. Angew. Chem. Int. Ed., 2018,57(10):2600-2604.
18. [18]
  Wang X, Li Q X, Shi P H, Fan J C, Min Y L, Xu Q J. Nickel nitride particles supported on 2D activated graphene-black phosphorus heterostructure: An efficient electrocatalyst for the oxygen evolution reaction[J]. Small, 2019,15(48)e1901530. doi: 10.1002/smll.201901530
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