Citation: Ru-Yi ZHANG, Xin CHEN, Yuan-Yuan GUO, Chong LIU, Kun-Lin HUANG. Structural diversity and luminescence properties of a series of complexes based on terpyridine-4-carboxylic acid[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(5): 928-938. doi: 10.11862/CJIC.2023.047 shu

Structural diversity and luminescence properties of a series of complexes based on terpyridine-4-carboxylic acid

1.
College of Chemistry, Chongqing Normal University, Chongqing 401331, China
2.
School of Chemical Engineering, Sichuan University, Chengdu 610065, China

Corresponding author: Xin CHEN, c00x00@cqnu.edu.cn Kun-Lin HUANG, kunlin@cqnu.edu.cn
Received Date: 13 October 2022
Revised Date: 19 January 2023

Figures(7)

A series of complexes constructed by 2,2′∶6,2″-terpyridine-4-carboxylic acid (Htpc), namely [Cr₂(tpc)₂ (HCOO)₂(OH)₂]·4H₂O (1), [Ba(tpc)₂(H₂O)₂]_n (2), [Zn₂(tpc)₂(NO₃)₂]_n (3), [Pb(Htpc)(NO₃)₂]·2H₂O (4), and [Rh(Htpc)Cl₃]·CH₃OH·H₂O (5), have been prepared under solvothermal conditions. Single crystal X-ray analysis reveals that the organic ligands took four different coordination fashions in 1-5. Complexes 1-5 show novel supramolecular networks through rich C—H…O/N hydrogen bonds and π…π contacts. The luminescence of the complexes was investigated and under 365 nm ultraviolet radiation the crystals of 2-5 displayed green, blue, purple-blue, and golden colors, respectively.
- terpyridine-4-carboxylic acid,
- complex,
- cluster,
- hydrogen bond,
- photoluminescence
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