Synthesis and catalytic activity in n-hexane isomerization of EU-1 zeolite
- Corresponding author: Dong-Sen MAO, dsmao@sit.edu.cn Jia-Wei TENG, tengjw@sinopec.com
Citation: Tong ZHANG, Jing SHI, Zhao-Teng XUE, Dong-Sen MAO, Jia-Wei TENG. Synthesis and catalytic activity in n-hexane isomerization of EU-1 zeolite[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(4): 659-670. doi: 10.11862/CJIC.2023.038
Casci J L, Lowe B M, Whittam T V. Zeolite EU‐1: EP81302343.9.1981‐12‐23.
Guillon E, Sanchez E. Modified EU‐1 zeolite and its use in the isomerization of aromatic C8 compounds: US20080281138.2008‐11‐13.
Patarin J, Guillon E, Rouleau L, Goergen S. Preparation of a porous composite material based on EU‐1 zeolite and its implementation in the isomerization of C8 aromatics: US20090062585.2009‐05‐05.
Teketel S, Skistad W, Benard S, Olsbye U, Lillerud K P, Beato P, Svelle S. Shape selectivity in the conversion of methanol to hydrocarbons: The catalytic performance of one-dimensional 10-ring zeolites: ZSM-22, ZSM-23, ZSM-48, and EU-1[J]. ACS Catal., 2011,2(1):26-37.
Hu S, Gong Y J, Xu Q H, Liu X L, Zhang Q, Zhang L L, Dou T. Highly selective formation of propylene from methanol over high-silica EU-1 zeolite catalyst[J]. Catal.Commun., 2012,28:95-99. doi: 10.1016/j.catcom.2012.08.011
Ahmed M H M, Masuda T, Muraza O. The role of acidity, side pocket, and steam on maximizing propylene yield from light naphtha cracking over one-dimensional zeolites: Case studies of EU-1 and disordered ZSM-48[J]. Fuel, 2019,258116034. doi: 10.1016/j.fuel.2019.116034
Souverijns W, Rombouts L, Martens J A, Jacobs P A. Molecular shape selectivity of EUO zeolites[J]. Microporous Mater., 1995,4(2):123-130.
Pradhan A R, Kotasthane A N, Rao B S. Isopropylation of benzene over EU-1 zeolite catalyst[J]. Appl.Catal., 1991,72(2):311-319. doi: 10.1016/0166-9834(91)85058-4
WANG J W, GUI S X, JING Z H. Advance in research on xylene isomerization catalyst[J]. Chemical Industry and Engineering Progress, 2004,23(3):244-247. doi: 10.3321/j.issn:1000-6613.2004.03.003
XU H Q, DU L J, LIU Q J, JIA L M. Study on the xylene isomerization performance of several molecular sieve catalysts[J]. Petroleum Processing and Petrochemicals, 2012,43(11):55-58. doi: 10.3969/j.issn.1005-2399.2012.11.013
Wu Q M, Liu X L, Zhu L F, Ding L H, Gao P, Wang X, Pan S X, Bian C Q, Meng X J, Xu J, Deng F, Maurer S, Müller U, Xiao F S. Solvent-free synthesis of zeolites from anhydrous starting raw solids[J]. J.Am.Chem.Soc., 2015,137(3):1052-1055. doi: 10.1021/ja5124013
Xu H, Zhu J, Wang X, Shen C, Meng S S, Zheng K, Lei C, Zhu L F. Sustainable route for synthesizing aluminosilicate EU‑1 zeolite[J]. Molecules, 2021,26(5):1462-1472. doi: 10.3390/molecules26051462
Cacsi J L, Whittam T V, Lowe B M//David O, Attilio B. Proceeding of the sixth international zeolites conference. Reno: Butterworths & Sevenoaks, 1983: 894‐904
Dodwell G W, Denkewicz R P, Sand L B. Crystallization of EU-1 and EU-2 in alkali and alkali-free systems[J]. Zeolites, 1985,5(3):153-157. doi: 10.1016/0144-2449(85)90023-5
Xu Q H, Gong Y J, Xu W J, Xu J, Deng F, Dou T. Synthesis of high-silica EU-1 zeolite in the presence of hexamethonium ions: A seeded approach for inhibiting ZSM-48[J]. J.Colloid Interface Sci., 2011,358(1):252-260. doi: 10.1016/j.jcis.2011.03.027
Agostini G, Lamberti C, Palin L, Milanesio M, Danilina N, Xu B, Janousch M, Bokhoven J A V. In situ XAS and XRPD parametric rietveld refinement to understand dealumination of Y zeolite catalyst[J]. J.Am.Chem.Soc., 2010,132(2):667-678. doi: 10.1021/ja907696h
LI X M, JIA J X, SUN X Y, FAN H F, WANG H. Effects of hydrothermal and nitric acid treatment on modified Y zeolite[J]. Pertochemical Technology, 2014,434(4):412-419. doi: 10.3969/j.issn.1000-8144.2014.04.010
Ahmed M H M, Muraza O, Amer A M A, Miyake K, Nishiyama N. Development of hierarchical EU-1 zeolite by sequential alkaline and acid treatments for selective dimethyl ether to propylene (DTP)[J]. Appl.Catal.A-Gen., 2015,497:127-134. doi: 10.1016/j.apcata.2015.03.011
Deldari H. Suitable catalysts for hydroisomerization of long-chain normal paraffins[J]. Appl.Catal.A-Gen., 2005,293:1-10. doi: 10.1016/j.apcata.2005.07.008
JIA X S, MA S T, SUO Y H, LIANG T, LI G X, WANG Y J. Research progress of C5-C8 alkanes isomerization catalysts[J]. Chemistry and Adhesion, 2017,39(2):126-131.
Guisnet M. "Ideal" bifunctional catalysis over Pt-acid zeolites[J]. Catal.Today, 2013,218:123-134.
Wang W, Liu C J, Wu W. Bifunctional catalysts for the hydroisomerization of n-alkanes: The effects of metal-acid balance and textural structure[J]. Catal.Sci.Technol., 2019,9:4162-4187. doi: 10.1039/C9CY00499H
Lyu Y C, Yu Z M, Yang Y, Wang X H, Zhao X X, Liu X M, Yan Z F. Metal-acid balance in the in-situ solid synthesized Ni/SAPO-11 catalyst for n-hexane hydroisomerization[J]. Fuel, 2019,243:398-405. doi: 10.1016/j.fuel.2019.01.013
Rao G N, Joshi P N, Kotasthane A N, Ratnasamy P. Synthesis and characterization of high-silica EU-1[J]. Zeolites, 1989,9(6):483-490. doi: 10.1016/0144-2449(89)90042-0
Jansen J C, Wilson S T. The preparation of oxide molecular sieves A.Synthesis of zeolites[J]. Stud.Surf.Sci.Catal., 2001,137:175-227.
Bu X H, Feng P Y, Stucky G D. Large-cage zeolite structures with multidimensional 12-ring channels[J]. Science, 1997,278(5346):2080-2085. doi: 10.1126/science.278.5346.2080
Lawton S L, Rohrbaugh W J. The framework topology of ZSM-48, a novel zeolite containing rings of three (Si Al)-O species[J]. Science, 1990,247(4948):1319-1322. doi: 10.1126/science.247.4948.1319
Davis M E, Lobo R F. Zeolite and molecular sieve synthesis[J]. Chem.Mater., 1992,4(4):756-768.
Karimi R, Bayati B, Aghdam N C, Ejtemaee M, Babaluo A A. Studies of the effect of synthesis parameters on ZSM-5 nanocrystalline material during template-hydrothermal synthesis in the presence of chelating agent[J]. Powder Technol., 2012,229:229-236.
Li X F, Liu X Z, Zhang Y T, Liu Y M, Sun X T, Ren P C, Gao M, Dou T. Controllable synthesis of EU-1 molecular sieve with high SiO2/Al2O3 ratios in thermodynamic stable sol system[J]. J.Porous Mater., 2016,23:1557-1565.
WU M L. Study on the effect of hydrothermal treatment on the acidity and hexene aromatization of Zn/ZSM‐5. Beijing: China University of Petroleum, 2019: 1‐77
Arnold A, Hunger M, Weitkamp J. Dry-gel synthesis of zeolites[Al]EU-1 and[Ga]EU-1[J]. Microporous Mesoporous Mater., 2004,8(1):205-213.
HAO J Q, ZHOU J, TENG J W, WANG Y D, XIE Z K. Effects of Pt/ZSM-5 metal-acid intimacy on the performance for hydroisomerization of n-hexane[J]. Chemical Reaction Engineering and Technology, 2022,38(4):310-317.
Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO3 for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO2 hydrogenation over a Mg-doped In2O3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO2 reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag3PO4/C3N5 Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
Jiaqi AN , Yunle LIU , Jianxuan SHANG , Yan GUO , Ce LIU , Fanlong ZENG , Anyang LI , Wenyuan WANG . Reactivity of extremely bulky silylaminogermylene chloride and bonding analysis of a cubic tetragermylene. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1511-1518. doi: 10.11862/CJIC.20240072
Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO2/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH2 supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO2 methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H2 production activity of BaTiO3 nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO2 cycloaddition over W18O49/NH2-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
The blue dotted lines are positions of EU‐1 characteristic peaks and the red dotted lines are positions of ZSM‐48 characteristic peaks
(a) E‐1; (b) E‐2; (c) E‐3
(a) x=160; (b) x=200; (c) x=300; (d) x=400; (e) x=600
(a) E‐10; (b) E‐11; (c) E‐12
The blue dotted lines are positions of EU‐1 characteristic peaks and the red dotted lines are positions of ZSM‐48 characteristic peaks
The blue dotted lines are positions of EU‐1 characteristic peaks and the red dotted lines are positions of ZSM‐48 characteristic peaks
(a) E‐21; (b) E‐22; (c) E‐24; (d) E‐26
(a) E‐6; (b) E‐9; (c) E‐12
Relative content of aluminum a=(10/x)/(10/x+y+r); Relative content of the directing agent b=y/(10/x+y+r); Relative content of seed c=r/(10/x+y+r)