Citation: Jia-Xuan WANG, Liang-Qing LI, Lei MA, Jin-Yin LÜ, Jian-Hua YANG, Jin-Ming LU. Preparation of mordenite membrane for pervaporation dehydration of acetic acid by a two-stage varying temperature crystallization hydrothermal method[J]. Chinese Journal of Inorganic Chemistry, ;2023, 39(1): 91-97. doi: 10.11862/CJIC.2022.270 shu

Preparation of mordenite membrane for pervaporation dehydration of acetic acid by a two-stage varying temperature crystallization hydrothermal method

1.
State Key Laboratory of Fine Chemicals, Institute of Adsorption and Inorganic Membrane, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China
2.
Key Laboratory of Functional Membranes and Energy Materials, School of Chemistry and Chemical Engineering, Huangshan University, Huangshan, Anhui 245041, China

Corresponding author: Jian-Hua YANG, yjianhua@dlut.edu.cn
Received Date: 9 June 2022
Revised Date: 11 November 2022

Figures(4)

Pervaporation (PV) has been favorably adopted in the industrial dehydration of various organic mixtures. In this work, mordenite membrane (MOR membrane) for PV dehydration of acetic acid was prepared by a two-stage varying temperature crystallization hydrothermal method from dilute synthesis solution with a high molar ratio of water to silica (n_H₂O/n_SiO₂). The effects of varying temperature crystallization time, n_H₂O/n_SiO₂, and the amount of fluorine ion on the morphology and separation performance of MOR membrane were investigated. The results showed that the above conditions have significant effects on the morphology, crystallinity, membrane thickness, and PV performance of the MOR membranes. The best performance MOR membrane was prepared at first-stage temperature (150 ℃, 18 h) and second-stage temperature (120 ℃, 6 h) with n_H₂O/n_SiO₂=60. The permeation flux and separation coefficient of the mass fraction of 50% acetic acid aqueous solution were 1.45 kg·m^-2·h^-1 and 1 008, respectively.
- mordenite membrane,
- varying temperature crystallization,
- pervaporation,
- dehydration of acetic acid mixture
1. [1]
  Lei Z G, Li C Y, Li Y X, Chen B H. Separation of acetic acid and water by complex extractive distillation[J]. Sep. Purif. Technol., 2004,36(2):131-138. doi: 10.1016/S1383-5866(03)00208-9
2. [2]
  Wang X P. Modified alginate composite membranes for the dehydration of acetic acid[J]. J. Membr. Sci., 2000,170(1):71-79. doi: 10.1016/S0376-7388(99)00361-0
3. [3]
  Jonquières A, Clément R, Lochon P, Néel J, Dresch M, Chrétien B. Industrial state-of-the-art of pervaporation and vapour permeation in the western countries[J]. J. Membr. Sci., 2002,206(1/2):87-117.
4. [4]
  Bowen T C, Noble R D, Falconer J L. Fundamentals and applications of pervaporation through zeolite membranes[J]. J. Membr. Sci., 2004,245(1/2):1-33.
5. [5]
  Smitha B, Suhanya D, Sridhar S, Ramakrishna M. Separation of organic- organic mixtures by pervaporation-A review[J]. J. Membr. Sci., 2004,241(1):1-21. doi: 10.1016/j.memsci.2004.03.042
6. [6]
  Wee S L, Tye C T, Bhatia S. Membrane separation process-pervaporation through zeolite membrane[J]. Sep. Purif. Technol., 2008,63(3):500-516. doi: 10.1016/j.seppur.2008.07.010
7. [7]
  Sander U, Soukup P. Design and operation of a pervaporation plant for ethanol dehydration[J]. J. Membr. Sci., 1988,36:463-475. doi: 10.1016/0376-7388(88)80036-X
8. [8]
  WANG J Q, YANG J H, CHEN Z, YIN D H. Research advances in zeolite membranes for pervaporation dehydration of organics in harsh environment[J]. Membrane Science and Technology, 2011,31(3):118-126. doi: 10.3969/j.issn.1007-8924.2011.03.018
9. [9]
  Raza W, Wang J X, Yang J H, Tsuru T. Progress in pervaporation membranes for dehydration of acetic acid[J]. Sep. Purif. Technol., 2021,262118338. doi: 10.1016/j.seppur.2021.118338
10. [10]
  Li Y S, Zhang X F, Wang J Q. Preparation for ZSM-5 membranes by a two-stage varying-temperature synthesis[J]. Sep. Purif. Technol., 2001,25(1/2/3):459-466.
11. [11]
  Kong C L, Lu J M, Yang J H, Wang J Q. Preparation of silicalite-1 membranes on stainless steel supports by a two-stage varyingtemperature in situ synthesis[J]. J. Membr. Sci., 2006,285(1/2):258-264.
12. [12]
  Zhu M H, Xia S L, Hua X M, Feng Z J, Hu N, Zhang F, Kumakiri I, Lu Z H, Chen X S, Kita H. Rapid preparation of acid-stable and high dehydration performance mordenite membranes[J]. Ind. Eng. Chem. Res., 2014,53(49):19168-19174. doi: 10.1021/ie501248y
13. [13]
  Li L Q, Yang J H, Li J J, Han P, Wang J X, Zhao Y, Wang J Q, Lu J M, Yin D H, Zhang Y. Synthesis of high performance mordenite membranes from fluoride-containing dilute solution under microwaveassisted heating[J]. J. Membr. Sci., 2016,512:83-92. doi: 10.1016/j.memsci.2016.03.056
14. [14]
  Wang S, Li L Q, Li J J, Wang J X, Pan E Z, Lu J M, Zhan Y, Yang J H. Sustainable synthesis of highly water-selective ZSM-5 membrane by wet gel conversion[J]. J. Membr. Sci., 2021,635119431. doi: 10.1016/j.memsci.2021.119431
15. [15]
  Wang J X, Wang L, Li L Q, Li J J, Raza W, Lu J M, Yang J H. A green synthesis of MOR zeolite membranes by wet gel conversion for dehydration of water-acetic acid mixtures[J]. Sep. Purif. Technol., 2022,286120311. doi: 10.1016/j.seppur.2021.120311
16. [16]
  Matsukata M, Sawamura K I, Shirai T, Takada M, Sekine Y, Kikuchi E. Controlled growth for synthesizing a compact mordenite membrane[J]. J. Membr. Sci., 2008,316(1/2):18-27.
17. [17]
  Zhu M H, Hua X M, Liu Y S, Hu H L, Li Y Q, Hu N, Kumakiri I, Chen X S, Kita H. Influences of synthesis parameters on preparation of acid-stable and reproducible mordenite membrane[J]. Ind. Eng. Chem. Res., 2016,55(47):12268-12275. doi: 10.1021/acs.iecr.6b02125
18. [18]
  Cundy C S, Cox P A. The hydrothermal synthesis of zeolites: History and development from the earliest days to the present time[J]. Chem. Rev., 2003,103(3):663-702. doi: 10.1021/cr020060i
19. [19]
  Lim I H, Schrader W, Schüth F. The formation of zeolites from solution-Analysis by mass spectrometry[J]. Microporous Mesoporous Mater., 2013,166:20-36. doi: 10.1016/j.micromeso.2012.04.059
20. [20]
  Chapman P D, Oliveira T, Livingston A G, Li K. Membranes for the dehydration of solvents by pervaporation[J]. J. Membr. Sci., 2008,318(1/ 2):5-37.
21. [21]
  Li G, Kikuchi E, Matsukata M. A study on the pervaporation of wateracetic acid mixtures through ZSM-5 zeolite membranes[J]. J. Membr. Sci., 2003,218(1/2):185-194.
22. [22]
  Li G, Kikuchi E, Matsukata M. Separation of water-acetic acid mixtures by pervaporation using a thin mordenite membrane[J]. Sep. Purif. Technol., 2003,32(1/2/3):199-206.
23. [23]
  Tanaka K, Yoshikawa R, Ying C, Kita H, Okamoto K I. Application of zeolite membranes to esterification reactions[J]. Catal. Today, 2001,67(1/2/3):121-125.
24. [24]
  Zhu M H, Kumakiri I, Tanaka K, Kita H. Dehydration of acetic acid and esterification product by acid-stable ZSM-5 membrane[J]. Micropo⁃ rous Mesoporous Mater., 2013,181:47-53. doi: 10.1016/j.micromeso.2012.12.044
25. [25]
  Tsuru T, Shibata T, Wang J, Lee H R, Kanezashi M, Yoshioka T. Pervaporation of acetic acid aqueous solutions by organosilica membranes[J]. J. Membr. Sci., 2012,421:25-31.
26. [26]
  Sato K, Sugimoto K, Kyotani T, Shimotsuma N, Kurata T. Synthesis, reproducibility, characterization, pervaporation and technical feasibility of preferentially b-oriented mordenite membranes for dehydration of acetic acid solution[J]. J. Membr. Sci., 2011,385:20-29.
1. [1]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
2. [2]
  Xinlong WANG , Zhenguo CHENG , Guo WANG , Xiaokuen ZHANG , Yong XIANG , Xinquan WANG . Enhancement of the fragile interface of high voltage LiCoO₂ by surface gradient permeation of trace amounts of Mg/F. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 571-580. doi: 10.11862/CJIC.20230259
3. [3]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
4. [4]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
5. [5]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
6. [6]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
7. [7]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(896)
HTML views(108)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142