Citation: De-Peng DENG, Ming-Hua CHEN, Yuan-Dong LIU, Bing-Fei QIAN, Wei-Min XIA, Jun-Ming YI. Crystal Structure of Four CyB₅Q[5]-Ca Complexes: The Different Coordination States in Different Anionic Environments[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(10): 1927-1938. doi: 10.11862/CJIC.2022.214 shu

Crystal Structure of Four CyB₅Q[5]-Ca Complexes: The Different Coordination States in Different Anionic Environments

School of Biology and Chemistry, Minzu Normal University of Xingyi, Xingyi, Guizhou 562400, China

Corresponding author: Ming-Hua CHEN, gui_zhou_chen@163.com
Received Date: 9 December 2021
Revised Date: 10 July 2022

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Four CyB₅Q[5]-Ca complexes (1-4) have been synthesized by the new member of the cucurbituril family (CyB₅Q[5]) and calcium ions in different anionic media. Their structures have been characterized by X-ray single-crystal diffraction. Their crystal structures show that complexes of different coordination types are generated in different environments of Cl^-, [ZnCl₄]^2-, [ZnCl₄]^2-+ClO₄^-, and ClO₄^-, respectively. The coordination number of complexes 1, 2, 3, and 4 are 6, 8, 7, and 6, respectively.
- cyclobutanocurbit[n]uril,
- cucurbituril-metal complex,
- supramolecular organic frameworks
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通讯作者: 陈斌, bchen63@163.com

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Crystal Structure of Four CyB5Q[5]-Ca Complexes: The Different Coordination States in Different Anionic Environments

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通讯作者: 陈斌, bchen63@163.com

Crystal Structure of Four CyB₅Q[5]-Ca Complexes: The Different Coordination States in Different Anionic Environments