Citation: Jun-Die ZHANG, Xiu-Juan JIANG, Zhi-Yin XIAO, Li-Mei CHEN, Xue-Mei WANG, Xiao-Ming LIU. Preventing CO-Releasing Systems from Forming Precipitates and Tuning CO-Releasing Rate via Ligand Exchange Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(8): 1593-1600. doi: 10.11862/CJIC.2022.151 shu

Preventing CO-Releasing Systems from Forming Precipitates and Tuning CO-Releasing Rate via Ligand Exchange Reaction

College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China

Corresponding author: Xiu-Juan JIANG, jiangxj@mail.zjxu.edu.cn Xiao-Ming LIU, xiaoming.liu@mail.zjxu.edu.cn
Received Date: 9 January 2022
Revised Date: 18 April 2022

Figures(6)

In this work, three water-soluble compounds (tiopronin, cysteamine, and mercaptoglycerol) which contain a thiol group have been used to initiate CO - release from a diiron hexacarbonyl complex [Fe₂(μ-SCH₂CH(OH)CH₂ (OH))₂(CO)₆] (1). To overcome forming precipitates during the CO-releasing process, we investigated using ethylene- diaminetetraacetic acid (EDTA) as the agent to solubilize products derived from the decomposition. Our results sug- gest that EDTA not only successfully prevents the CO-releasing system from forming precipitates, but also synergis- tically facilitates the CO-release from complex 1. Despite the fact that the chosen ligands possess a thiol functional group, their behaviors in promoting the CO-release from complex 1 are rather different, which can be exploited to tune the CO-releasing rate in potential applications.
- CO-releasing molecules,
- diiron carbonyl complex,
- ligand exchange reaction,
- precipitation prevention,
- CO-release tuning
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