Citation: Gang XU, Xiao-Nan JIANG, Wei-Xiang CHEN. Preparation of ZnS@C/rGO Composite for Electrochemical Reversible Lithium Storage[J]. Chinese Journal of Inorganic Chemistry, ;2022, 38(5): 891-900. doi: 10.11862/CJIC.2022.090 shu

Preparation of ZnS@C/rGO Composite for Electrochemical Reversible Lithium Storage

Department of Chemistry, Zhejiang University, Hangzhou 310027, China

Corresponding author: Wei-Xiang CHEN, weixiangchen@zju.edu.cn
Received Date: 23 December 2021
Revised Date: 11 March 2022

Figures(8)

ZnS@C/reduce graphene oxide (rGO) composite was prepared by solvothermal reaction-hydrothermal treatment route. ZnS nanocrystal coated by amorphous carbon (ZnS@C) was prepared by the first-step solvothermal reaction, then ZnS@C/rGO was prepared by the second-step hydrothermal treatment. The morphology and microstructure of samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). Electrochemical test results demonstrated that the as-prepared ZnS@C/rGO composite exhibited significantly enhanced electrochemical lithium storage performance in comparison to ZnS@C and ZnS/rGO. At the current density of 100 mA·g^-1, ZnS@C/rGO electrode delivered the reversible specific capacity of 1 101 mAh·g^-1 and 1 569 mAh·g^-1, respectively, at the 1st and 100th cycle. After 1 200 cycles at the different current densities, the reversible specific capacity of 1 096 mAh·g^-1 was remained at 2.0 A·g^-1, indicating its stable long-cycle performance.
- lithium-ion battery,
- solvothermal reaction,
- hydrothermal treatment,
- amorphous carbon,
- reduced graphene oxide
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