Citation: Jiao ZHAO, Zhi-Yuan WANG, Hai-Lang JIA, Rui-Xin CHEN, Rui LIU. Preparation and Performance of N and S Co-doped Graphene Loaded Cobalt Sulfide Nanoparticles Oxygen Evolution Electrocatalyst[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(10): 1793-1800. doi: 10.11862/CJIC.2021.216 shu

Preparation and Performance of N and S Co-doped Graphene Loaded Cobalt Sulfide Nanoparticles Oxygen Evolution Electrocatalyst

1.
School of Chemical and Environmental Engineering, Jiangsu University of Technology, Changzhou, Jiangsu 213001, China
2.
PLA Army Academy of Artillery and Air Defense, Hefei 230031, China

Corresponding author: Hai-Lang JIA, jiahailang85@126.com
Received Date: 30 April 2021
Revised Date: 7 August 2021

Figures(6)

The three-dimensional N and S co-doped graphene loaded cobalt sulfide nanoparticles oxygen evolution electrocatalyst (CoS/N/S/rGO) was prepared by using D-glucosamine as the Co dispersant and carbon source, thiourea as the nitrogen source and sulfur source, and NaCl as the template, achieving N and S co-doping and uniformly loading two kinds of nanoparticles Co₉S₈ and Co₄S₃. CoS/N/S/rGO had good oxygen reduction reaction (ORR) activity with initial potential of 960 mV and half-wave potential of 815 mV, respectively, which was similar to commercial Pt/C. In addition, CoS/N/S/rGO showed obvious four-electron transfer characteristics and ultra-low hydrogen peroxide production rate. Compared with Pt/C based zinc-air battery, CoS/N/S/rGO based zinc-air battery showed higher constant current discharge performance and better stability in 6 mol·L^-1 KOH and 0.2 mol·L^-1 Zn(CH₃COO)₂ alkaline electrolyte.
- oxygen reduction reaction,
- template method,
- electrocatalyst,
- zinc-air battery
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