Citation: Meng XU, Xiao-Cong YU, Xue-Fen LIU, Hao CHEN, Jin-Xuan FAN, Tian-Qi WANG, Qing-An WU, Shu-Ping LUO. Macrocyclic Arenes Derived Phenanthrolines: Design, Synthesis and Application at Heteroleptic Copper Complexes for Photocatalytic Hydrogen Evolution from Water[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(9): 1597-1605. doi: 10.11862/CJIC.2021.188 shu

Macrocyclic Arenes Derived Phenanthrolines: Design, Synthesis and Application at Heteroleptic Copper Complexes for Photocatalytic Hydrogen Evolution from Water

Meng XU ^{1, #} ,
Xiao-Cong YU ^{1, #} ,
Xue-Fen LIU ² ,
Hao CHEN ¹ ,
Jin-Xuan FAN ¹ ,
Tian-Qi WANG ¹ ,
Qing-An WU ¹ ,
Shu-Ping LUO ^1,,

1.
State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, China
2.
Qianjiang College, Hangzhou Normal University, Hangzhou 310018, China

Corresponding author: Shu-Ping LUO, Luoshuping@zjut.edu.cn
Received Date: 9 February 2021
Revised Date: 14 July 2021

Figures(9)

A series of macrocyclic arenes derived phenanthrolines have been designed and synthesized, which could form a series of novel heteroleptic copper photosensitizers CuPS 1~CuPS 6 with Xantphos as phosphorus ligands. The photosensitive activity of CuPS 1~CuPS 6 was studied in homogeneous photocatalytic water reduction system for hydrogen production. The research results showed that 1-naphthyl was the preferred substituent and the turnover number (TON) of CuPS 3 for hydrogen production was up to 957. Through theoretical calculation and comparative analysis, a larger dihedral angle of the 1-naphthyl substituent and the phenanthroline nucleus has a better steric effect to protect the excited state of the copper complex. Thus, CuPS 3 displayed a higher fluorescence quantum yield (0.036) and a longer excited state lifetime (1.36 μs).
- macrocyclic arene,
- phenanthroline,
- copper photosensitizer,
- photocatalytic water splitting,
- hydrogen evolution
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