Citation: Xiao-Wei WU, Tian GUI, Zhi-Cheng YAN, Yu-Qin LI, Xiang-Shu CHEN. Synthesis of High-Flux Mordenite Membranes by Binary Cations System for Pervaporation Dehydration of Acetic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(8): 1482-1492. doi: 10.11862/CJIC.2021.163 shu

Synthesis of High-Flux Mordenite Membranes by Binary Cations System for Pervaporation Dehydration of Acetic Acid

Institute of Advanced Materials (IAM), State-Province Joint Engineering Laboratory of Zeolite Membrane Materials, College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China

Corresponding author: Yu-Qin LI, liyuqin1122@jxnu.edu.cn Xiang-Shu CHEN, cxs66cn@jxnu.edu.cn
Received Date: 2 March 2021
Revised Date: 12 May 2021

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The influences of alkali-metal cations on growth and pervaporation (PV) performance of mordenite membranes were investigated in detail with multiple characterization techniques. The results show that the morphology and quality of mordenite membrane are greatly influenced by Li⁺, Na⁺, K⁺ and Cs⁺ as well as the mixed Na⁺-Li⁺, Na⁺-K⁺ and Na⁺-Cs⁺. It is found that alkali-metal cations play a structure-directing role on the nucleation when aluminosilicate is rearranged by facilitating the dissolution of silicon in initial gel, and then play the structure formation effect for constructing mordenite framework. Na⁺ has a significant acceleration effect on mordenite crystallization while Li⁺, K⁺ and Cs⁺ exhibit a slower crystallization rate in the equal crystallization time. The replacement of a small amount of Na⁺ with K⁺ in synthesis gel can improve the hydrophilicity of membrane surface. Especially, the Na⁺/K⁺ ratio (n_Na⁺/n_K⁺) of 2 in synthesis gel resulted in the formation of denser and more hydrophilic mordenite membranes with higher PV performances. For separation of a HAc/H₂O mixture containing mass fraction of 90% HAc at 90℃, the membrane showed a high permeation flux of 2.67 kg·m^-2·h^-1 and a high separation factor of about 4 000. Moreover, the mordenite membrane displayed a long-term acid stability in pervaporation of a 90% HAc/H₂O mixture at 90℃ for 240 h.
- mordenite membrane,
- alkali-metal cations,
- high-flux,
- long-term acid stability,
- dehydration
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