Citation: Cui-Xin HUANG, Jia GU, Wan-Ming XIONG, Jin-Zhu CHEN, Xu-Liang NIE, Xin-Chen SHANGGUAN. Synthesis, Crystal Structures and Antibacterial Activities of Two Complexes of Zn(Ⅱ)/Cd(Ⅱ) Assembled by 4-Carboxymethoxycinnamic Acid Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(7): 1197-1203. doi: 10.11862/CJIC.2021.153 shu

Synthesis, Crystal Structures and Antibacterial Activities of Two Complexes of Zn(Ⅱ)/Cd(Ⅱ) Assembled by 4-Carboxymethoxycinnamic Acid Ligand

Cui-Xin HUANG ¹ ,
Jia GU ² ,
Wan-Ming XIONG ^{2, 3} ,
Jin-Zhu CHEN ^{2, 3} ,
Xu-Liang NIE ^{1, 2, 3,,} ,
Xin-Chen SHANGGUAN ⁴

1.
College of Agronomy, Jiangxi Agricultural University, Nanchang 330045, China
2.
College of Science, Jiangxi Agricultural University, Nanchang 330045, China
3.
Key Laboratory of Chemical Utilization of Plant Resources of Nanchang, Nanchang 330045, China
4.
Jiangxi Institute for Drug Control, Nanchang 330029, China

Corresponding author: Xu-Liang NIE, niexuliang1981@163.com
Received Date: 29 December 2020
Revised Date: 10 May 2021

Figures(9)

Two Zn(Ⅱ)/Cd(Ⅱ) complexes, [Zn(CMOPAA)(Phen)(H₂O)]_n (1) and [Cd(CMOPAA)(Phen)]_n (2), (H₂CMOPAA =4-carboxymethoxy-3-phenylpropenoate and Phen=1, 10-phenanthroline) were synthesized with H₂CMOPAA ligand by solvothermal condition and structurally characterized by element analysis, IR, TGA (thermogravimetric analysis) and single crystal X-ray diffraction. Complex 1 crystalizes in the monoclinic system, space group P2₁/n with a= 0.698 84(8) nm, b=1.751 16(19) nm, c=1.655 49(18) nm, β=95.165(10)°, V=2.017 7(4) nm³. The asymmetric unit of complex 1 consists of one Zn(Ⅱ) ion, one CMOPAA^2- ligand, one Phen ligand and one coordinated H₂O. Zn(Ⅱ) ion is a six-coordinated distorted octahedral configuration. The carboxyl group of CMOPAA^2- ligand connects the adjacent zinc ions to form a helical one-dimensional chain. Hydrogen bonds link the adjacent one-dimensional chains to form a two-dimensional network. Complex 2 crystalizes in the triclinic system, space group P1 with a=0.988 28(16) nm, b =1.040 08(17) nm, c=1.096 15(18) nm, α=72.213(2)°, β=74.439(2)°, γ=71.265(2)°, V=0.997 8(3) nm³. The asymmetric unit of complex 2 consists of one Cd(Ⅱ) ion, one CMOPAA^2- ligand and one Phen ligand. Cd(Ⅱ) ion is a seven-coordinated twisted single-cap triangular prism configuration. The carboxyl group of CMOPAA^2- ligand connects the adjacent cadmium ions to form a parallelogram 26-membered large ring structure. The 26-membered large rings are linked to a one-dimensional band-like structure. The thermal stabilities and antibacterial activities of complexes 1 and 2 were studied. CCDC: 2054460, 1; 2068057, 2
- 4-carboxymethoxy-3-phenylpropenoate,
- complex,
- synthesis,
- crystal structure,
- antibacterial activities
1. [1]
  YI J P, HE J, SHAN C J. Principle, Diagnosis and Treatment of Com-mon Plant Diseases. Beijing: China Agricultural University Press, 2012.
2. [2]
  KANG Z S. Plant Protection, 2010, 36(3): 9-12 doi: 10.3969/j.issn.0529-1542.2010.03.003
3. [3]
  ZHANG Y, ZHANG Q, HE R P, XUAN S B, AN Z X, ZHENG Y. Journal of Shanxi Agricultural Sciences, 2015, 43(1): 75-78, 100 doi: 10.3969/j.issn.1002-2481.2015.01.21
4. [4]
  Fan J Y, Luo Y, Michailides T J, Guo L Y. Pest. Manage. Sci. , 2014, 70(2): 245-251 doi: 10.1002/ps.3549
5. [5]
  FENG X Z, XIAO Z Q, LU P Y, FAN G R, WANG Z D. Chemistry and Industry of Forest Products, 2019, 39(1): 35-40 doi: 10.3969/j.issn.0253-2417.2019.01.005
6. [6]
  WANG T Q, XIAO Z Q, WANG Z D, FAN G R, CHEN S X. Journal of Jiangxi Normal University (Natural Science Edition), 2018, 42(5): 482-485
7. [7]
  Burt S. Int. J. Food Microbiol. , 2004, 94(3): 223-253 doi: 10.1016/j.ijfoodmicro.2004.03.022
8. [8]
  DONG A J, LIU H C, LIU B, KE W C, LUO C H, CHEN Y K. Food Science and Technology, 2017, 42(5): 253-256
9. [9]
  Orlikova B, Legrand N, Panning J, Dicato M, Diederich M. Advances in Nutrition and Cancer: Vol. 159. Zappia V, Panico S, Russo G, Budillon A, Della Ragione F. ed. , Berlin, Heidelberg: Springer, 2014: 123-143
10. [10]
  Guzman J D, Mortazavi P N, Munshi T, Evangelopoulos D, McHugh T D, Gibbons S, Malkinson J, Bhakta S. Med. Chem. Comm. , 2014, 5(1): 47-50 doi: 10.1039/C3MD00251A
11. [11]
  Nauseef W M. Biochim. Biophys. Acta Gen. Sub. , 2014, 1840(2): 757-767 doi: 10.1016/j.bbagen.2013.04.040
12. [12]
  LI X F, FENG X Q, YANG S, ZHU Y C. Journal of Materials Science and Engineering, 2016, 34(4): 624-628
13. [13]
  ZHOU X J, ZHOU K N, WANG Z L, XIAO T J, ZHAO X Q, LI Q X. Chinese J. Inorg. Chem. , 2013, 29(9): 1870-1876
14. [14]
15. [15]
16. [16]
  Guo C M, Yi L Y, Pan L, You Y, Nie X L. Z. Kristallogr. -New Cryst. Struct. , 2021, 236: 569-571 doi: 10.1515/ncrs-2020-0634
17. [17]
  APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA, 2005.
18. [18]
  Sheldrick G M. SHELXS-2014, Program for Crystal Structure Solution, University of Göttingen, Germany, 2014.
19. [19]
  Sheldrick G M. SHELXL-2014, Program for Crystal Structure Refinement, University of Göttingen, Germany, 2014.
20. [20]
  ZHANG C Y, FU J D, WEN Y H. Chinese J. Inorg. Chem. , 2011, 27(11): 2308-2312
1. [1]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
2. [2]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
3. [3]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
4. [4]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
5. [5]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
6. [6]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
7. [7]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
8. [8]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
9. [9]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
10. [10]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
11. [11]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
12. [12]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
13. [13]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
14. [14]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
15. [15]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
16. [16]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
17. [17]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
18. [18]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
19. [19]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
20. [20]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(612)
HTML views(84)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142