Citation: Rong-Ge GUO, Ying-Li LI, Ze-Yuan HU, Mei-Yu SHI, Yi-Dong MIAO, Yan-Wei SUI, Ji-Qiu QI, Fu-Xiang WEI, Yao-Jian REN, Zhen-Zhen ZHAN, Jin-Long LIU, Zhi SUN, Mei-Hua ZHOU, Dong-Mei MENG. In-Situ Growth of NiCo-Layered Double Hydroxides Nanosheets Deposited on Carbon Fiber Cloth for High-Performance Asymmetric Supercapacitors[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(5): 886-898. doi: 10.11862/CJIC.2021.078 shu

In-Situ Growth of NiCo-Layered Double Hydroxides Nanosheets Deposited on Carbon Fiber Cloth for High-Performance Asymmetric Supercapacitors

1.
Jiangsu Province High-Efficiency Energy Storage Technology and Equipment Engineering Laboratory, School of Materials and Physics, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China
2.
Jiangsu FERY Battery Technology Co., Ltd., Xuzhou, Jiangsu 221116, China

Corresponding author: Yan-Wei SUI, wyds123456@outlook.com Zhi SUN, sunzhi108@outlook.com
Received Date: 8 September 2020
Revised Date: 28 January 2021

Figures(10)

The NiCo-layered double hydroxide (LDH) was prepared directly on different carbon fiber substrates by potentiostatic deposition. This method did not need to add any binder, which can prevent the phenomenon of conductivity reduction due to the resistance of the binder. In the layered crystal structure of NiCo-LDH, the positively charged host layer and the interlayer charge compensating anion can promote ion diffusion between electrode materials, so that the active sites can be efficiently utilized. In this paper, an electrode material with a wrinkled structure was synthesized by a potentiostatic deposition technique. Benefiting from the folded lamellar structure features, this composite material (NiCo-LDH/carbon fiber cloth) had sterling specific capacitance (1 387.5 F·g^-1 at 1 A·g^-1). In addition, with the composite as the positive electrode and the rGO coated on the surface of nickel foam (NF) as negative material, the assembled asymmetric supercapacitor (ASC) presented superb electrochemical performance. ASC had an energy density of 26.6 Wh·kg^-1 and a power density of 850.4 W·kg^-1 at 1 A·g^-1. The energy density remained 14.9 Wh·kg^-1 as the maximum power density (8 500.3 W·kg^-1).
- layer double hydroxides,
- electrodeposition,
- current collector,
- asymmetric supercapacitor,
- nanostructures,
- energy conversion
1. [1]
  Yadav A A, Hunge Y M, Kulkarni S B. Ultrason Sonochem, 2019, 58: 104663 doi: 10.1016/j.ultsonch.2019.104663
2. [2]
  Daneshvar N, Khataee A R, Ghadim R A, Rasoulifard M H. J. Hazard. Mater. , 2007, 148(3): 566-572 doi: 10.1016/j.jhazmat.2007.03.028
3. [3]
  Alshahrie A, Ansari M O. Electron. Mater. Lett. , 2019, 15(2): 238-246 doi: 10.1007/s13391-018-00107-6
4. [4]
  Wen Y L, Kierzek K, Chen X C, Gong J, Liu J, Niu R. Waste Manage. , 2019, 87: 691-700 doi: 10.1016/j.wasman.2019.03.006
5. [5]
  Yu L P, Chen G Z. Front. Chem. , 2019, 7(15): 272
6. [6]
  Yadav A A, Lokhande A C, Kim J H, Lokhande C D. J. Colloid Interface Sci. , 2016, 473: 22-27 doi: 10.1016/j.jcis.2016.03.051
7. [7]
  Natarajan S, Lee Y S, Aravindan V. Chem Asian J. , 2019, 14(7): 936-951 doi: 10.1002/asia.201900030
8. [8]
  Wang W, Chen L J, Qi J Q, Sui Y, He Y, Meng Q. J. Mater. Sci. Mater. Electron. , 2018, 29(3): 2120-2130 doi: 10.1007/s10854-017-8124-7
9. [9]
  Chen H, Zhang H, Zhang Y, Wang Y, Su X T, Zhang L J. Chem. Eng. J. , 2019, 375: 121926 doi: 10.1016/j.cej.2019.121926
10. [10]
  Guo J Z, Gu Z Y, Zhao X X, Wang M Y, Yang X, Yang Y, Li W H, Wu X L. Adv. Energy Mater. , 2019, 9(38): 1902056 doi: 10.1002/aenm.201902056
11. [11]
  Cheng Y H, Van M J, Lataire P. International Review of Electrical Engineering (IREE), 2008, 3(1): 198-207
12. [12]
  Ma Y Y, Yuan W Y, Bai Y H, Wu H, Cheng L F. Carbon, 2019, 154: 292-300 doi: 10.1016/j.carbon.2019.07.095
13. [13]
  Chen Y J, Qu B H, Hu L L, Xu Z, Li Q H, Wang T H. Nanoscale, 2013, 5(20): 9812-9820 doi: 10.1039/c3nr02972g
14. [14]
  Jiao Z M, Wu Q Q, Cardon L, Qiu J. J. Nanosci. Nanotechnol. , 2020, 20(4): 2316-2323 doi: 10.1166/jnn.2020.17363
15. [15]
  Chen W Q, Wang J, Ma K Y, Li M, Guo S H, Liu F. Appl. Surf. Sci. , 2018, 451: 280-288 doi: 10.1016/j.apsusc.2018.04.254
16. [16]
  Meng Q F, Cai K F, Chen Y X, Chen L D. Nano Energy, 2017, 36: 268-285 doi: 10.1016/j.nanoen.2017.04.040
17. [17]
  Huang C H, Hu Y Z, Jiang S P, Chen H C. Electrochim. Acta, 2019, 325: 134936 doi: 10.1016/j.electacta.2019.134936
18. [18]
  Liu L L, Guan T, Fang L, Wu F, Lu Y, Luo H J. J. Alloys Compd. , 2018, 763: 926-934 doi: 10.1016/j.jallcom.2018.05.358
19. [19]
  Gao Zan, Wang J, Li Z S, Yang W L, Wang B, Hou M J. Chem. Mater. , 2011, 23(15): 3509-3516 doi: 10.1021/cm200975x
20. [20]
  Jagadale A D, Guan G Q, Li X M, Du X, Ma X L, Hao X G. J. Power Sources, 2016, 306: 526-534 doi: 10.1016/j.jpowsour.2015.12.097
21. [21]
  Feng Y Y, Li Y J, Yang W, Huang H B. J. Nanosci. Nanotechnol. , 2020, 20(2): 1260-1268 doi: 10.1166/jnn.2020.16983
22. [22]
  Memon J, Sun J H, Meng D L, Ouyang W Z, Memon M A, Huang Y. J. Mater. Chem. A, 2014, 2(14): 5060-5067 doi: 10.1039/c3ta14613h
23. [23]
  Li T, Li R, Luo H. J. Mater. Chem. A, 2016, 4(48): 18922-18930 doi: 10.1039/C6TA08032D
24. [24]
  Zardkhoshoui A M, Davarani S H. J. Alloys Compd. , 2018, 750: 515-522 doi: 10.1016/j.jallcom.2018.04.027
25. [25]
  Cao J M, Li L, Xi Y D, Li J Z, Pan X X, Chen D. Sustain. Energy Fuels, 2018, 2(6): 1350-1355 doi: 10.1039/C8SE00123E
26. [26]
  Hu H H, Qi J Q, Sui Y W, Zhou Y, Wei F, He Y. J. Mater. Sci. Mater. Electron. , 2017, 28(14): 10720-10729 doi: 10.1007/s10854-017-6848-z
27. [27]
  Yin Q, Li D P, Zhang J, Zhao Y J, Wang C, Han J B. Appl. Surf. Sci. , 2019, 487: 1-8 doi: 10.1016/j.apsusc.2019.04.253
28. [28]
  Li Y L, Shan L N, Sui Y W, Qi J Q, Wei F X, He Y Z. J. Mater. Sci. Mater. Electron. , 2019, 30(14): 13360-13371 doi: 10.1007/s10854-019-01703-4
29. [29]
  Nagaraju G, Raju G R, Ko Y H, Yu J S. Nanoscale, 2016, 8(2): 812-825 doi: 10.1039/C5NR05643H
30. [30]
  Liang X, Long G H, Fu C W, Pang M J, Xi Y L, Li J Z. Chem. Eng. J. , 2018, 345: 186-195 doi: 10.1016/j.cej.2018.03.104
31. [31]
  Hou B H, Wang Y Y, Ning Q L, Li W H, Xi X T, Yang Y, Liang H J, Feng X, Wu X L. Adv. Mater. , 2019, 31(40): 1903125 doi: 10.1002/adma.201903125
32. [32]
  Li H G, Wang S B, Feng M J. Chin. Chem. Lett. , 2019, 30(2): 529-532 doi: 10.1016/j.cclet.2018.06.024
33. [33]
  Sekhar S C, Nagaraju G, Yu J S. Nano Energy, 2017, 36: 58-67 doi: 10.1016/j.nanoen.2017.04.019
34. [34]
  Ke Q Q, Guan C, Zhang X, Zheng M R, Zhang Y W, Cai Y Q, Zhang H, Wang J. Adv. Mater. , 2017, 29(5): 1604164 doi: 10.1002/adma.201604164
35. [35]
  Kulkarni S B, Jagadale A D, Kumbhar V S, Bulakhe R N, Joshi S S. Int. J. Hydrogen Energy, 2013, 38(10): 4046-4053 doi: 10.1016/j.ijhydene.2013.01.047
36. [36]
  Zhang L J, Hui K N, Hui K S. Electrochim. Acta, 2015, 186: 522-529 doi: 10.1016/j.electacta.2015.11.024
37. [37]
  Chen H, Hu L F, Chen M, Yan Y, Wu L M. Adv. Funct. Mater. , 2014, 24(7): 934-942 doi: 10.1002/adfm.201301747
38. [38]
  Jia H A, Wang Z Y, Zheng X H, Lin J H, Liang H Y, Cai Y F, Qi J L, Cao J, Feng J C, Fei W D. Chem. Eng. J. , 2018, 351: 348-355 doi: 10.1016/j.cej.2018.06.113
39. [39]
  Shahrokhian S, Rahimi S, Mohammadi R. Int. J. Hydrogen Energy, 2018, 43(4): 2256-2267 doi: 10.1016/j.ijhydene.2017.12.019
40. [40]
  Zhao J W, Chen J L, Xu S, Shao M F, Zhang Q, Wei F, Ma J, Wei M, Evans D G, Duan X. Adv. Funct. Mater. , 2014, 24(20): 2938-2946 doi: 10.1002/adfm.201303638
41. [41]
  Dai C S, Chien P Y, Lin J Y, Chou S W, Wu W K, Li P H, Wu K Y, Lin T W. ACS Appl. Mater. Interfaces, 2013, 5(22): 12168-12174 doi: 10.1021/am404196s
42. [42]
  Tang Y F, Liu Y Y, Yu S X, Guo W C, Mu S C, Wang H C, Zhao Y F, Hou L, Fan Y Q, Gao F M. Electrochim. Acta, 2015, 161: 279-289 doi: 10.1016/j.electacta.2015.02.095
43. [43]
  Wang G R, Li Y B, Jin Z L. New J. Chem. , 2020, 44(18): 7528-7540 doi: 10.1039/D0NJ00611D
44. [44]
  Li S B, P J, Li F B, Zhang L, Chai D F, Zhang Z F, Xin J J. Dalton Trans. , 2020, 49(29): 10203-10211 doi: 10.1039/D0DT00251H
45. [45]
  Kulandaivalu S, Hussein M Z, Jaafar A M, Abdah M, Azman M, Sulaiman Y. RSC Adv. , 2019, 9(69): 40478-40486 doi: 10.1039/C9RA08134H
46. [46]
  Verma S, Gupta V, Khosla A, Kumar S, Arya S. Nanotechnology, 2020, 31(24): 245401 doi: 10.1088/1361-6528/ab7b07
47. [47]
  Liu L, Hu X, Zeng H Y, Yi M Y, Shen S G, Xu S, Cao Y, Du J Z. J. Mater. Sci. Technol. , 2019, 35(8): 1691-1699 doi: 10.1016/j.jmst.2019.04.003
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