Citation: Qiang HE, Xiao-Gang SUN, Jing-Yi ZOU, Rui LI. Three-Dimensional Porous Carbon Loading Tin Oxide and Cooperating with Lithium Fluoride to Prepare High Performance Lithium Ion Anode[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(3): 473-481. doi: 10.11862/CJIC.2021.059 shu

Three-Dimensional Porous Carbon Loading Tin Oxide and Cooperating with Lithium Fluoride to Prepare High Performance Lithium Ion Anode

School of Mechanical and Electrical Engineering, Nanchang University, Nanchang 330031, China

Corresponding author: Xiao-Gang SUN, xiaogangsun@163.com
Received Date: 16 September 2020
Revised Date: 7 January 2021

Figures(8)

New porous carbon nanosheets/carbon nanotubes (PC/CNT) materials showed a rich hierarchical pore structure with high tin oxide (SnO₂) loading. The three-dimensional structure formed by the cross-linking of PC and CNT can improve Li⁺ transmission rate and electron conduction. In addition, lithium fluoride (LiF) doped in the electrode can not only reduce the charge transfer resistance of the SnO₂-PC/CNT-LiF electrode, but also supplement the Li⁺ consumed during the formation of the SEI film, reduce the irreversible capacity and enhance the stability of the SEI film. The first reversible specific capacity of SnO₂-PC/CNT-LiF electrode reached 1 642.98 mAh·g^-1 at current density of 100 mA·g^-1, and the utilization rate of active material was as high as 90.12%. After 100 cycles, the specific discharge capacity still reached above 745.11 mAh·g^-1, and the coulombic efficiency remained above 95.1%, showing excellent rate and cycle performance.
- tin oxide,
- porous carbon nanosheets,
- carbon nanotubes,
- lithium fluoride
1. [1]
  Waag W, Käbitz S, Sauer D U. Appl. Energy, 2013, 102: 885-897 doi: 10.1016/j.apenergy.2012.09.030
2. [2]
  Wang Y, Zeng H C, Lee J Y. Adv. Mater. , 2006, 18(5): 645-649 doi: 10.1002/adma.200501883
3. [3]
  Li L M, Yin X M, Liu S, Wang Y G, Chen L B, Wang T H. Electrochem. Commun. , 2010, 12(10): 1383-1386 doi: 10.1016/j.elecom.2010.07.026
4. [4]
  Chen J S, Cheah Y L, Chen Y T, Jayaprakash N, Madhavi S, Yang Y H, Lou X W. J. Phys. Chem. C, 2009, 113(47): 20504-20508 doi: 10.1021/jp908244m
5. [5]
  Fu S T, Wu Q L, He S M, Tong S F, Yang X F, Meng Y Y, Wu M M. ChemElectroChem, 2018, 5(17): 2341-2347 doi: 10.1002/celc.201800631
6. [6]
  Lou X W, Wang Y, Yuan C L, Lee J Y, Archer L A. Adv. Mater. , 2006, 18(17): 2325-2329 doi: 10.1002/adma.200600733
7. [7]
  Yang L N, Chen K X, Dong T, Wang Z, Li G M, Zhang Y L, Zhang L P. J. Nanosci. Nanotechnol. , 2016, 16(2): 1768-1774 doi: 10.1166/jnn.2016.10703
8. [8]
  Han F, Li W C, Li M R, Lu A H. J. Mater. Chem. , 2012, 22(19): 96459651
9. [9]
  Yao J, Shen X, Wang B, Liu H K, Wang G X. Electrochem. Commun. , 2009, 11(10): 1849-1852 doi: 10.1016/j.elecom.2009.07.035
10. [10]
  An W L, Gao B, Mei S X, Xiang B, Fu J J, Wang L, Zhang Q B, Chu P K, Huo K F. Nat. Commun. , 2019, 10(1): 1447 doi: 10.1038/s41467-019-09510-5
11. [11]
  Liu X L, Xu P C, Li X R, Peng Y T, Le Z Y. J. Mater. Sci. , 2018, 53: 15621-15630 doi: 10.1007/s10853-018-2727-0
12. [12]
  He C L, Xiao Y, Dong H W, Liu Y L, Zheng M T, Xiao K, Liu X R, Zhang H R, Lei B F. Electrochim. Acta, 2014, 142: 157-166 doi: 10.1016/j.electacta.2014.07.077
13. [13]
  Bhattacharya P, Kota M, Suh D H, Roh K C, Park H S. Adv. Energy Mater. , 2017, 7(17): 1700331 doi: 10.1002/aenm.201700331
14. [14]
  Liang Y R, Zhang W C, Wu D C, Ni Q Q, Zhang M Q. Adv. Mater. Interfaces, 2018, 5(14): 1800430 doi: 10.1002/admi.201800430
15. [15]
  Wen Z H, Wang Q, Zhang Q, Li J H. Adv. Funct. Mater. , 2010, 17(15): 2772-2778
16. [16]
  Liang J, Yu X Y, Zhou H, Wu H B, Ding S J, Lou X W. Angew. Chem. Int. Ed. , 2014, 126(47): 13017-13021 doi: 10.1002/ange.201407917
17. [17]
  Xia L, Wang S Q, Liu G X, Ding L X, Li D D, Wang H H, Qiao S Z. Small, 2015, 12(7): 853-859
18. [18]
  Xu D W, Xin S, You Y, Li Y T, Cong H P, Yu S H. ChemNanoMat, 2016, 2(7): 712-718 doi: 10.1002/cnma.201600065
19. [19]
  Luo C, Niu S, Zhou G, Lu W, Li B, Kang F, Yang Q H. Chem. Commun. , 2016, 52(57): 12143-12146
20. [20]
  Guo J C, Xu Y H, Wang C S. Nano Lett. , 2011, 11(10): 4288-4294 doi: 10.1021/nl202297p
21. [21]
  Sun L, Si H C, Zhang Y X, Shi Y, Wang K, Liu J G, Zhang Y H. J. Power Sources, 2019, 415: 126-135 doi: 10.1016/j.jpowsour.2019.01.063
22. [22]
  Wang K, Huang J G. Appl. Surf. Sci. , 2019, 476: 293-302 doi: 10.1016/j.apsusc.2019.01.094
23. [23]
  Zhou Z P, Zhang H, Zhou Y, Qiao H, Gurung A, Naderi R, Elbohy H, Smirnova A L, Lu H T, Chen S L, Qiao Q Q. Sci. Rep. , 2017, 7(1): 1-9 doi: 10.1038/s41598-016-0028-x
24. [24]
  Liu H, Hu R Z, Sun W, Zeng M Q, Liu J W, Yang L C, Zhu M. J. Power Sources, 2013, 242(15): 114-121
25. [25]
  Li Y Y, Zhang H Y, Chen Y M, Shi Z C, Cao X G, Guo Z P, Shen P K. ACS Appl. Mater. Interfaces, 2016, 8(1): 197-207 doi: 10.1021/acsami.5b08340
26. [26]
  Quinlan R A, Cai M Z, Outlaw R A, Butler S M, Miller J R, Mansour A N. Carbon, 2013, 64: 92-100 doi: 10.1016/j.carbon.2013.07.040
27. [27]
  Shao Q G, Tang J E, Sun Y G, Li J, Zhang K, Yuan J S, Zhu D M, Qin L C. Nanoscale, 2017, 9(13): 4439-4444 doi: 10.1039/C6NR09689A
28. [28]
  Huang M, Feng M, Li H J, Huang P, Su Q M, Zhang F M, Du G H. Mater. Lett. , 2017, 209(15): 260-263
29. [29]
  Sennu P, Aravindan V, Lee Y S. Chem. Eng. J. , 2017, 324: 26-34 doi: 10.1016/j.cej.2017.05.003
30. [30]
  Von A N, Rosechenthaler G V, Winter M, Cekic-Laskovic I. Angew. Chem. Int. Ed. , 2019, 58(45): 15978-16000 doi: 10.1002/anie.201901381
31. [31]
  Hang T, Mukoyama D, Nara H, Takami N, Momma T, Osaka T. J. Power Sources, 2013, 222(15): 442-44
1. [1]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
2. [2]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
3. [3]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
4. [4]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
5. [5]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
6. [6]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
7. [7]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
8. [8]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
9. [9]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
10. [10]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
11. [11]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
12. [12]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
13. [13]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
14. [14]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
15. [15]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
16. [16]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
17. [17]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
18. [18]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
19. [19]
  Di WU , Ruimeng SHI , Zhaoyang WANG , Yuehua SHI , Fan YANG , Leyong ZENG . Construction of pH/photothermal dual-responsive delivery nanosystem for combination therapy of drug-resistant bladder cancer cell. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1679-1688. doi: 10.11862/CJIC.20240135
20. [20]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(835)
HTML views(182)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142