Citation: Gang LI, Zhe FENG, Rong-Rong NIE, Dun-Ru ZHU. Syntheses and Crystal Structures of Two Copper Complexes Based on Thienyl and Pyridyl Substituted Triaryltriazoles[J]. Chinese Journal of Inorganic Chemistry, ;2021, 37(3): 561-568. doi: 10.11862/CJIC.2021.054 shu

Syntheses and Crystal Structures of Two Copper Complexes Based on Thienyl and Pyridyl Substituted Triaryltriazoles

Gang LI ¹ ,
Zhe FENG ¹ ,
Rong-Rong NIE ¹ ,
Dun-Ru ZHU ^{1, 2,,}

1.
College of Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 211816, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China

Corresponding author: Dun-Ru ZHU, zhudr@njtech.edu.cn
Received Date: 21 September 2020
Revised Date: 18 November 2020

Figures(5)

Two new copper(Ⅱ) complexes, trans-[Cu(L¹)₂(MeOH)₂](ClO₄)₂ (1) and trans-[Cu(L²)₂(ClO₄)₂]·2MeCN (2) (L¹=3-(2-pyridyl)-4-phenyl-5-(2-thienyl)-1, 2, 4-triazole, L²=3-(2-pyridyl)-4-(p-chlorophenyl)-5-(2-thienyl)-1, 2, 4triazole), were synthesized and structurally characterized by FT-IR, elemental analyses, single-crystal X-ray crystallography and powder X-ray diffraction. Both 1 and 2 crystallize in monoclinic system with a space group P2₁/c. Xray crystallography analysis reveals that the copper ion in 1 and 2 sits in a distorted octahedral environment[CuN₄O₂] with two MeOH in the trans-position in 1 but two ClO₄^- in the trans-position in 2. Each L ligand in the equatorial plane adopts a chelating bidentate mode through the pyridyl N atom and one triazole N atom, while the thienyl group does not coordinate. 2 contains two MeCN guest molecules which produce π-π stacking interactions with the triazole ring. In 1 and 2 there are some intermolecular O-H…O, C-H…O and C-H…N hydrogen bonds and C-H…π interactions, linking the mononuclear complexes to form a 3D framework. CCDC: 2423470, 1; 2423471, 2.
- synthesis,
- Cu(Ⅱ) complex,
- crystal structure,
- triaryltriazole
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