Citation: ZHANG Qi, ZHANG Guang-Wei, CHENG Jun-Yan, LU Wen-Xin, WANG Peng. Synthesis, Crystal Structure and Fluorescence Emission Properties of Cd(Ⅱ) and Pb(Ⅱ) MOFs Based on Hydroxyethoxy Isophthalate Acid[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(11): 2063-2070. doi: 10.11862/CJIC.2020.247 shu

Synthesis, Crystal Structure and Fluorescence Emission Properties of Cd(Ⅱ) and Pb(Ⅱ) MOFs Based on Hydroxyethoxy Isophthalate Acid

1.
College of Chemical and Biological Engineering, Shandong University of Science and Technology, Qingdao, Shandong 266590, China
2.
College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, China

Corresponding author: LU Wen-Xin, lwx08lwx@126.com WANG Peng, pengwang@sdust.edu.cn
Received Date: 18 March 2020
Revised Date: 7 September 2020

Figures(10)

Cadmium(Ⅱ) and lead(Ⅱ) based three-dimensional metal-organic frameworks (MOFs), namely {[Cd(L)(H₂O)₂]· 1.5H₂O}_n (1) and[Pb(L)·H₂O]_n (2), have been obtained through hydrothermal synthesis method using dimethyl 5-(2-hydroxyethoxy) isophthalic acid (Me₂L) as a precursor and metal acetate. The crystal structures of two MOFs were revealed by single-crystal X-ray diffraction analysis and further confirmed by infrared spectrum (IR) and element analysis (EA). The XRD analysis of the MOFs ensured the single-crystal phase of the MOFs. The fluorescence emission property of two MOFs and H₂L in the solid-state was investigated. Compared to the emission spectrum of Me₂L, the emission maximum of compounds 1 and 2 all had red-shift but 2 shifted more severe.CCDC: 1986790, 1;1986793, 2.
- 5-(2-hydroxyethoxy) isophthalate,
- metal-organic frameworks,
- crystal structure,
- fluorescence emission
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沈阳化工大学材料科学与工程学院沈阳 110142