Citation: WANG Yong-Juan, ZHOU Yu-Ming, HE Man, HE Qiang, ZHONG Yang-Yang. Layer-by-Layer Assembly and Infrared Emissivity of (LDH/DNA/LDH/LTO)_n Hybrid Films[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(10): 1977-1987. doi: 10.11862/CJIC.2020.221 shu

Layer-by-Layer Assembly and Infrared Emissivity of (LDH/DNA/LDH/LTO)_n Hybrid Films

School of Chemistry and Chemical Engineering, Southeast University, Jiangsu Optoelectronic Functional Materials and Engineering Laboratory, Nanjing 211189, China

Corresponding author: WANG Yong-Juan, wangyongjuan0630@126.com
Received Date: 31 March 2020
Revised Date: 6 August 2020

Figures(8)

Herein, by using sequentially electrostatic layer-by-layer (LBL) deposition method, the artificialdesigned hybrid films were fabricated through the alternatively assemble of negatively charged layered titanium oxide (LTO) nanosheets and DNA molecules with positively charged layered double hydroxide (LDH) nanosheets. The infrared emissivity values at the wavelength of 8~14 μm of the as-synthesized samples were investigated. The X-ray diffraction (XRD) results demonstrate that the (LDH/DNA/LDH/LTO)_n hybrid films were orderly stacked on the substrate in the normal direction, in which the DNA molecules and LTO nanosheets were accommodated as monolayer between the LDH nanosheets layers, respectively. It can be seen from the scanning electron microscope (SEM) and atomic force microscope (AFM) images that the surface morphology of the film was uniform and continuous. The energy dispersive X-ray spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS) analysis verify the composition, the homogenous element distribution, and the well-ordered structure in the multilayer films. This multilayered hybrid film with tetra-layer units possessed a low infrared emissivity value of 0.419 based on the synergistic effect of its multi-components, the interfacial interaction between different layers and the uniform and smooth surface. These results clearly demonstrate that the ordered LBL assembly of the artificial designed hybrid film is quite effective in decreasing the infrared emissivity value.
- LDH,
- DNA,
- layered titanium oxide,
- layer-by-layer,
- organic-inorganic hybrid composites,
- infrared emissivity
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Layer-by-Layer Assembly and Infrared Emissivity of (LDH/DNA/LDH/LTO)n Hybrid Films

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通讯作者: 陈斌, bchen63@163.com

Layer-by-Layer Assembly and Infrared Emissivity of (LDH/DNA/LDH/LTO)_n Hybrid Films