Citation: WANG Ying-Ying, TONG Hong-Bo, ZHOU Mei-Su. Pentanuclear Sn(Ⅱ) Guanidinate Complex: Synthesis, Structure, and Catalytic Activity for Addition of Arylamines into N, N'-Diisopropylcarbodiimide[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(8): 1567-1572. doi: 10.11862/CJIC.2020.178 shu

Pentanuclear Sn(Ⅱ) Guanidinate Complex: Synthesis, Structure, and Catalytic Activity for Addition of Arylamines into N, N'-Diisopropylcarbodiimide

Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, China

Corresponding author: ZHOU Mei-Su, mszhou@sxu.edu.cn
Received Date: 20 December 2019
Revised Date: 20 April 2020

Figures(3)

A pentanuclear Sn(Ⅱ) guanidinate complex[PhNC(NMe)₂N(H)SnCl]₂[PhNC(NMe)₂NSnCl]₂Sn (1) was synthesized via the reaction of PhN(Li)SiMe₃ and anhydrous tin(Ⅱ) chloride. It was well structurally characterized by ¹H NMR, ¹³C NMR, elemental analysis, and X-ray single crystal crystallography techniques. Complex 1 is an active catalyst in the addition reaction of arylamines into N, N'-diisopropylcarbodiimide giving guanidinates. CCDC:1954650.
- tin(Ⅱ),
- guanidinate,
- structure,
- catalytic addition
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