Citation: ZOU Xue-Yan, ZHAO Yan-Bao, ZHANG Zhi-Jun. A Facile Method to Prepare Hydroxyapatite Nanotubes and Immobilization Activities Against Heavy Metal Ions in Solutions[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(4): 747-754. doi: 10.11862/CJIC.2020.084 shu

A Facile Method to Prepare Hydroxyapatite Nanotubes and Immobilization Activities Against Heavy Metal Ions in Solutions

ZOU Xue-Yan ^1,2 ,
ZHAO Yan-Bao ^1,3,4,, ,
ZHANG Zhi-Jun ^1,2,4,,

1.
Engineering Research Center for Nanomaterials, Henan University, Kaifeng, Henan 475004, China
2.
Key Laboratory for Monitor and Remediation of Heavy Metal Polluted Soils of Henan Province, Jiyuan, Henan 459000, China
3.
National & Local Joint Engineering Research Center for Applied Technology of Hybrid Nanomaterials, Henan University, Kaifeng, Henan 475004, China
4.
Collaborative Innovation Center of Nano Functional Materials and Applications of Henan Province, Henan University, Kaifeng, Henan 475004, China

Corresponding author: ZHAO Yan-Bao, zhaoyb902@henu.edu.cn ZHANG Zhi-Jun, zhangzj09@126.com
Received Date: 22 August 2019
Revised Date: 25 February 2020

Figures(6)

Hydroxyapatite nanotubes (HAP NTs) were synthesized by a facile method, which were 20~40 nm in length and had a large surface area of 56 m²·g^-1. Then the prepared HAP NTs were employed to immobilize Pb²⁺, Cd²⁺, Cu²⁺, Co²⁺, Ni²⁺, Zn²⁺, and Hg²⁺ in aqueous solution and the as-prepared HAP NTs showed a high immobilization capacity. In addition, the desorption rate of the prepared HAP NTs on seven heavy metal ions were all less than 1%, which showed a strong stability. The experimental data was analyzed by the Langmuir and Freundlich isotherm models. The obtained results from the application of the two equations showed that the adsorption equilibrium was best fitted with a Langmuir model and monolayer adsorption capacity was 958.28 mg·g^-1, which showed a perfect immobilization property. The adsorption mechanisms were further studied by energy dispersive X-ray spectrum (EDS) and X-ray diffraction (XRD) patterns and the results showed that the adsorption mechanism was the dissolution of HAP NTs and the precipitation of a more stable Pb₅(PO₄)₃(OH) when the amount of Pb²⁺ ions in solution was sufficient. Our study confirmed the possibilities of using HAP NTs to treat Pb-contaminated wastewater in the environmental pollution management.
- hydroxyapatite,
- nanotubes,
- immobilization,
- mechanism,
- heavy metal ions,
- environmental chemistry,
- hydrothermal synthesis
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