Citation: ZHAI Jia-Xin, LI Guo-Hua, GAN Si-Ping, ZHANG Xue-Ming, ZHU Meng-Meng, ZHANG Xiao-Rui, HU En-Yan. Catalytic Performance of CuCo/BNNSs Nanocatalysts for Hydrolysis of Solid State Hydrogen Storage Material Ammonia Borane[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(2): 241-252. doi: 10.11862/CJIC.2020.018 shu

Catalytic Performance of CuCo/BNNSs Nanocatalysts for Hydrolysis of Solid State Hydrogen Storage Material Ammonia Borane

School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, China

Corresponding author: LI Guo-Hua, ligh@hebut.edu.cn
Received Date: 19 July 2019
Revised Date: 9 November 2019

Figures(17)

CuCo bimetallic nanoparticles were supported on few layer boron nitride nanosheets (BNNSs) prepared by polyvinylpyrrolidone (PVP)-assisted ion intercalation, and a highly dispersed copper-cobalt/boron nitride nanosheets (donated as CuCo/BNNSs) nanocatalyst with an average particle size of 2.7 nm was obtained with a method of co-reduction. The structure and morphology of the carrier and catalyst were characterized by atomic force microscope (AFM), X-ray diffraction (XRD), fourier transform infrared (FTIR), Raman spectra (Raman), X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM) and high resolution transmission electron microscopy (HRTEM), and the catalytic performance of CuCo/BNNSs was studied. The results showed that Cu_0.5Co_0.5/BNNSs nanocatalysts exhibited high catalytic activity towards the hydrolysis of ammonia borane (AB, NH₃BH₃) at room temperature when pH value was 14 and the turn over frequency (TOF) reached 104.52 mol_H₂·mol_metal^-1·min^-1 due to the highly efficient quadruple synergistic effect between Cu, Co, BNNSs and OH^-. Moreover, the CuCo/BNNSs nanocatalyst also had good stability and high catalytic activity was maintained after 6 cycles.
- boron nitride nanosheets,
- CuCo alloys,
- supported catalysts,
- cooperative effects,
- ammonia borane,
- hydrogen production
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