Citation: ZHONG Wei, XIA Ying-Fan, ZHAI Hang-Ling, GAO Yue, LI Shi-Hui, LÜ Chun-Xin. Preparation by Co-precipitation Method and Photocatalytic Performances on the Degradation of Dyes of Ce³⁺-Doped Nano-ZnO[J]. Chinese Journal of Inorganic Chemistry, ;2020, 36(1): 40-52. doi: 10.11862/CJIC.2020.006 shu

Preparation by Co-precipitation Method and Photocatalytic Performances on the Degradation of Dyes of Ce³⁺-Doped Nano-ZnO

ZHONG Wei ^1,2,, ,
XIA Ying-Fan ² ,
ZHAI Hang-Ling ² ,
GAO Yue ² ,
LI Shi-Hui ² ,
LÜ Chun-Xin ^2,,

1.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China
2.
College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China

Corresponding author: ZHONG Wei, weizhong@mail.zjxu.edu.cn LÜ Chun-Xin, chunxin0923@163.com
Received Date: 29 August 2019
Revised Date: 15 October 2019

Figures(16)

A series of nano-ZnO doped with different amounts of cerium were prepared by co-precipitation method with Zn(NO₃)₂·6H₂O and Ce(NO₃)₃·6H₂O as raw materials. The as-made samples were characterized by powder X-ray diffraction (XRD), infrared spectroscopy (IR), scanning electron microscope (SEM), energy dispersive spectrometer (EDS) and UV-visible diffuse reflectance spectroscopy (UV-Vis DRS). Some samples were further characterized by X-ray photoelectron spectroscopy (XPS) and photoluminescence (PL). Photocatalytic activity of these materials toward photodegradation of methylene blue (MB) was evaluated under UV and sunlight irradiation, respectively. It was found that the sample with 3% Ce³⁺ doped ZnO, named as ZnO-3% Ce, exhibited highest photocatalytic activity among the prepared samples and its MB-degradation efficiency was over 98%. Then, the sample of ZnO-3% Ce was selected to further evaluate its photocatalytic activity toward photodegradation of rhodamine B (RhB) and methyl orange (MO) under both UV and sunlight irradiation. The results showed that the sample of ZnO-3% Ce presented good photodegradation activity under both UV and sunlight condition. The order of photodegradation efficiency under sunlight irradiation was as follows:MB > RhB > MO, while the photocatalytic activity under UV irradiation was increased by the following order RhB > MB > MO. The stability of ZnO-3%Ce catalyst was studied by cyclic experiments. The results showed that the photodegradation efficiency still retained more than 97% after three cycles, suggesting that the catalyst maintained its structure and component and presented good stability and application prospect.
- nano-ZnO,
- rare earth element,
- doping,
- photocatalysis,
- degradation,
- dyes
1. [1]
  Bolisetty S, Peydayesh M, Mezzenga R. Chem. Soc. Rev., 2019, 48(2):463-487 doi: 10.1039/C8CS00493E
2. [2]
  Natarajan S, Bajaj H C, Tayade R J. J. Environ. Sci.-China, 2018, 65(3):201-222
3. [3]
  Lu F, Astruc D. Coord. Chem. Rev., 2018, 356:147-164 doi: 10.1016/j.ccr.2017.11.003
4. [4]
  Basheer A. J. Mol. Liq., 2018, 261:583-593 doi: 10.1016/j.molliq.2018.04.021
5. [5]
  Santhosh C, Velmurugan V, Jacob G, et al. Chem. Eng. J., 2016, 306:1116-1137 doi: 10.1016/j.cej.2016.08.053
6. [6]
  Gaya U I, Abdullah A H. J. Photochem. Photobiol. C, 2008, 9(1):1-12
7. [7]
  Lewis N S. Science, 2007, 315(5813):798-801 doi: 10.1126/science.1137014
8. [8]
  Monfort O, Plesch G. Environ. Sci. Pollut. Res., 2018, 25(20):19362-19379 doi: 10.1007/s11356-018-2437-9
9. [9]
  Regulacio M D, Han M Y. Acc. Chem. Res., 2016, 49(3):511-519 doi: 10.1021/acs.accounts.5b00535
10. [10]
  Kumari V, Mittal A, Jindal J, et al. Front. Mater. Sci., 2019, 13(1):1-22 doi: 10.1007/s11706-019-0453-4
11. [11]
  Samadi M, Zirak M, Naseri A, et al. Res. Chem. Intermed., 2019, 45(4):2197-2254 doi: 10.1007/s11164-018-03729-5
12. [12]
  Wang X L, Ahmad M, Sun H Y. Materials, 2017, 10(11):1304-1327 doi: 10.3390/ma10111304
13. [13]
  Adnan M A M, Julkapli N M, Hamid S B A. Rev. Inorg. Chem., 2016, 36(2):77-104
14. [14]
  Koodziejczak-Radzimska A, Jesionowski T. Materials, 2014, 7(4):2833-2881 doi: 10.3390/ma7042833
15. [15]
  Chong M N, Jin B, Chow C W K, et al. Water Res., 2010, 44(10):2997-3027 doi: 10.1016/j.watres.2010.02.039
16. [16]
  QUAN Wei-Lei, ZHANG Jin-Min, SHEN Jun-Hai, et al. Chinese J. Inorg. Chem., 2015, 31(8):1626-1636
17. [17]
  SU Bi-Tao, HU Chang-Lin, ZUO Xian-Wei, et al. Chinese J. Inorg. Chem., 2010, 26(1):96-100
18. [18]
  Linsebigler A L, Lu G Q, Yates J T. Chem. Rev., 1995, 95(3):735-758 doi: 10.1021/cr00035a013
19. [19]
  Ismail I M I, Aslam M, Almeelbi T, et al. RSC Adv., 2014, 4(31):16043-16046 doi: 10.1039/C4RA00097H
20. [20]
  YU Chang-Lin, YANG Kai, YU Ji-Mei, et al. Acta Phys.-Chim. Sin., 2011, 27(2):505-512 doi: 10.3866/PKU.WHXB20110230
21. [21]
  Su Y M, Li J B, Luo Z Z, et al. RSC Adv., 2016, 6(9):7403-7408 doi: 10.1039/C5RA24492G
22. [22]
  Hui A P, Liu J L, Ma J Z. Colloid. Surface. A, 2016, 506:519-525 doi: 10.1016/j.colsurfa.2016.07.016
23. [23]
  Yayapao O, Thongtem S, Phuruangrat A, et al. Ceram. Int., 2013, 39(S1):S563-S568
24. [24]
  Guo Y, Cao X B, Lan X M, et al. J. Phys. Chem. C, 2008, 112:8832-8838
25. [25]
  Kadam A, Dhabbe R, Gophane A, et al. J. Photochem. Photobiol. B, 2016, 154:24-33 doi: 10.1016/j.jphotobiol.2015.11.007
26. [26]
  Yousefi R, Jamali-Sheini F, Cheraghizade M, et al. Mater. Sci. Semicond. Process., 2015, 32:152-159 doi: 10.1016/j.mssp.2015.01.013
27. [27]
  Liang Y M, Guo N, Li L L, et al. RSC Adv., 2015, 5(74):59887-59894 doi: 10.1039/C5RA08519E
28. [28]
  http://srdata.nist.gov/xps/selEnergyType.aspx
29. [29]
  Jiang J J, Zhang K, Chen X D, et al. J. Alloys Compd., 2017, 699:907-913 doi: 10.1016/j.jallcom.2017.01.036
30. [30]
  Bera P, Anandan C. RSC Adv., 2014, 4(108):62935-62939 doi: 10.1039/C4RA09882J
31. [31]
  Konstantinou I K, Albanis T A. Appl. Catal. B, 2004, 49(1):1-14
32. [32]
  Li D, Huang J F, Cao L Y, et al. Ceram. Int., 2014, 40(2):2647-2653 doi: 10.1016/j.ceramint.2013.10.061
1. [1]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
2. [2]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
3. [3]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
4. [4]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
5. [5]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
6. [6]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
7. [7]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
8. [8]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
9. [9]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
10. [10]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
11. [11]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
12. [12]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
13. [13]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
14. [14]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
15. [15]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
16. [16]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
17. [17]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
18. [18]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
19. [19]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
20. [20]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398

Get Citation

PDF

XML

Metrics

PDF Downloads(17)
Abstract views(1129)
HTML views(255)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation by Co-precipitation Method and Photocatalytic Performances on the Degradation of Dyes of Ce3+-Doped Nano-ZnO

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation by Co-precipitation Method and Photocatalytic Performances on the Degradation of Dyes of Ce³⁺-Doped Nano-ZnO