Citation: CHEN Hui-Xian, LIU Chun-Yu, ZHOU Xuan, CHEN Min-Min, NI Chun-Yan, LANG Jian-Ping. One-Dimensional Coordination Polymers Based on a Tripyridine Olefin Ligand: Synthesis, Structures and Photoelectronic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(11): 2038-2044. doi: 10.11862/CJIC.2019.228 shu

One-Dimensional Coordination Polymers Based on a Tripyridine Olefin Ligand: Synthesis, Structures and Photoelectronic Properties

Suzhou Key Laboratory of Precision Transformation of Resource Molecules, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China

Corresponding author: LIU Chun-Yu, 928483592@qq.com NI Chun-Yan, chunyan89.ok@163.com LANG Jian-Ping, jplang@suda.edu.cn
Received Date: 2 August 2019
Revised Date: 12 September 2019

Figures(6)

The reactions of dipyridin-2-yl-(4-(2-pyridin-4-yl-vinyl)-phenyl)-amine (ppvppa) with various silver(Ⅰ) salts afforded three one-dimensional (1D) coordination polymers {[Ag(ppvppa)]BF₄}_n (1), {[Ag(ppvppa)]PF₆}_n (2) and {[Ag(ppvppa)]NO₃}_n (3). When analogous reactions of ppvppa with Ni(Ⅱ) salt was carried out under solvothermal conditions, another 1D coordination polymer {[Ni(ppvppa)(2, 3-NDC)(H₂O)]·2H₂O}_n (4) was obtained. Complexes 1~4 were characterized by elemental analysis, infrared spectrum (IR), thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD) and single crystal X-ray diffraction. Complexes 1~3 have similar 1D cationic chain structures in which the dimeric[Ag(ppvppa)]₂ units are interconnected by ppvppa ligands. Complex 4 holds a double chain structure in which the[Ni₂(ppvppa)₂(H₂O)₂] units are interlinked by pairs of 2, 3-NDC ligands. In the solid state, Ag(Ⅰ)-based complexes 1~3 showed good luminescent properties while no luminescence was observed for Ni(Ⅱ)-based complex 4. Complexes 1 and 4 as representative samples showed relatively prompt, rapid anodic photocurrent responses, which were steady and reproducible after ten on/off cycles. The photocurrent values were calculated to be 2 μA for 1 and 6 μA for 4, respectively, which were greater than that observed for a blank ITO electrode.
- coordination polymers,
- crystal structures,
- fluorescence properties,
- photocurrent responses
1. [1]
  Li J R, Kuppler R J, Zhou H C. Chem. Soc. Rev., 2009, 38:1477-1504 doi: 10.1039/b802426j
2. [2]
  Zhang H D, Deria P, Farha O K, et al. Energy Environ. Sci., 2015, 8:1501-1510 doi: 10.1039/C5EE00808E
3. [3]
  Kaye S S, Dailly A, Yaghi O M, et al. J. Am. Chem. Soc., 2007, 129:14176-14177 doi: 10.1021/ja076877g
4. [4]
  Chen L N, Li H Q, Zhan W W, et al. ACS Appl. Mater. Interfaces, 2016, 8:31059-31066 doi: 10.1021/acsami.6b11567
5. [5]
  Li F L, Shao Q, Huang X Q, et al. Angew. Chem. Int. Ed., 2018, 57:1888-1892 doi: 10.1002/anie.201711376
6. [6]
  Kanoo P, Matsuda R, Sato H, et al. Inorg. Chem., 2013, 52:10735-10737 doi: 10.1021/ic401924d
7. [7]
  Song X Z, Song S Y, Zhao S N, et al. Adv. Funct. Mater., 2014, 24:4034-4041 doi: 10.1002/adfm.201303986
8. [8]
  Yang S Y, Deng X L, Jin R F, et al. J. Am. Chem. Soc., 2014, 136:558-561 doi: 10.1021/ja409272p
9. [9]
  Nath N K, Runevski T, Lai C Y, et al. J. Am. Chem. Soc., 2015, 137:13866-13875 doi: 10.1021/jacs.5b07806
10. [10]
  Shi Y X, Zhang W H, Abrahams B F, et al. Angew. Chem. Int. Ed., 2019, 58:9453-9458 doi: 10.1002/anie.201903757
11. [11]
  Yeung M C L, Yam V W W. Chem. Soc. Rev., 2015, 44:4192-4202 doi: 10.1039/C4CS00391H
12. [12]
  McQuade D T, Pullen A E, Swager T M. Chem. Rev., 2000, 100:2537-2574 doi: 10.1021/cr9801014
13. [13]
  Wang X, Zhang M M, Hao X L, et al. Cryst. Growth Des., 2013, 13:3454-3462 doi: 10.1021/cg400353j
14. [14]
  Wen T, Zhang D X, Zhang J. Inorg. Chem., 2013, 52:12-14 doi: 10.1021/ic302273h
15. [15]
  Weng W, Chen P N, He S S, et al. Angew. Chem. Int. Ed., 2016, 55:6140-6169 doi: 10.1002/anie.201507333
16. [16]
  Liu C Y, Xu L Y, Ren Z G, et al. Cryst. Growth Des., 2017, 17:4826-4834 doi: 10.1021/acs.cgd.7b00766
17. [17]
  Seki T, Tokodai N, Omagari S, et al. J. Am. Chem. Soc., 2017, 139:6514-6517 doi: 10.1021/jacs.7b00587
18. [18]
  Pang J, Tao Y, Freiberg S, et al. J. Mater. Chem., 2002, 12:206-212 doi: 10.1039/b105422h
19. [19]
  Toal S J, Trogler W C. J. Mater. Chem., 2006, 16:2871-2883 doi: 10.1039/b517953j
20. [20]
  Yang W Y, Schmider H, Wu Q G, et al. Inorg. Chem., 2000, 39:2397-2404 doi: 10.1021/ic991436m
21. [21]
  Pang J, Marcotte E J P, Seward C, et al. Angew. Chem. Int. Ed., 2001, 40:4042-4045 doi: 10.1002/1521-3773(20011105)40:21<4042::AID-ANIE4042>3.0.CO;2-0
22. [22]
  Chen M M, Zhou X, Li H X, et al. Cryst. Growth Des., 2015, 15:2753-2760 doi: 10.1021/acs.cgd.5b00095
23. [23]
  Wang J F, Liu S Y, Liu C Y, et al. Dalton Trans., 2016, 45:9294-9306 doi: 10.1039/C6DT01211F
24. [24]
  CrysAlisPro, Ver. 1.171.37.31, Agilent Technologies UK Ltd. Yarnton, England, 2013.
25. [25]
  Sheldrick G M. Struct. Chem., 2015, 71:3-8
26. [26]
  Spek A L. J. Appl. Crystallogr., 2003, 36:7-13 doi: 10.1107/S0021889802022112
27. [27]
  Su C Y, Cai Y P, Chen C L, et al. J. Am. Chem. Soc., 2003, 125:8595-8613 doi: 10.1021/ja034267k
28. [28]
  WANG Yan, CHEN Fei-Fei, HU Xiao-Shuang, et al. Chinese J. Inorg. Chem., 2019, 35(2):225-235
29. [29]
  LIANG Chu-Xin, LIU Zheng, LIANG Qiu-Qun, et al. Chinese J. Inorg. Chem., 2019, 35(7):1130-1138
30. [30]
  Wenger O S. Chem. Rev., 2013, 113:3686-3733 doi: 10.1021/cr300396p
31. [31]
  Wang C, Xie Z G, deKrafft K E, et al. J. Am. Chem. Soc., 2011, 133:13445-13454 doi: 10.1021/ja203564w
32. [32]
  Xu L Y, Yang W, Liu C F, et al. CrystEngComm, 2018, 20:4049-4057 doi: 10.1039/C8CE00715B
1. [1]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
2. [2]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
3. [3]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
4. [4]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
5. [5]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
6. [6]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
7. [7]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
8. [8]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
9. [9]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
10. [10]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
11. [11]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
12. [12]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
13. [13]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
14. [14]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
15. [15]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
16. [16]
  Zhenzhong MEI , Hongyu WANG , Xiuqi KANG , Yongliang SHAO , Jinzhong GU . Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1795-1802. doi: 10.11862/CJIC.20240081
17. [17]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
18. [18]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
19. [19]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
20. [20]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(1332)
HTML views(95)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142