Synthesis, Characterization, Fluorescence Properties and Herbicidal Activity of Bis(Substituted Salicylaldehyde) Carbohydrazide and Its Benzyltin Complexes
- Corresponding author: KUANG Dai-Zhi, hnkcq@qq.com
Citation: FENG Yong-Lan, YANG Chun-Lin, ZHANG Fu-Xing, KUANG Dai-Zhi. Synthesis, Characterization, Fluorescence Properties and Herbicidal Activity of Bis(Substituted Salicylaldehyde) Carbohydrazide and Its Benzyltin Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(10): 1737-1745. doi: 10.11862/CJIC.2019.205
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Bn=benzyl; T1: X=S, R1=NEt2, R2=H; T2: X=S, R1=H, R2=Me; T3: X=O, R1=H, R2=Me; T4: R1=NEt2, R2=H
cT4=1.072 μmol·L-1, λex=304 nm
Inset: plot of maximum fluorescence intensity of T4 in DMF-H2O mixtures with different volume fractions of water
Target plant: 1 Portulaca oleracea L., 2 Amaranthus spinosus L., 3 Cassia tora L., 4 Brassica campestris L. ssp. chinensis var. utilis Tsen et Lee and 5 Amaranthus tricolor L.; Effects of ligand on plants: 1~5, effects of complex on plants: 6~10; R represents the root of a plant and S represents the stalk; Inset: change of the growth promotion rate of Amaranthus tricolor L. with the concentration of complex T4