Citation: LIU Yang, PAN Zhao-Rui, SHI Xiao-Ran, LANG Lei-Ming. One-Step Controllable Synthesis of Silica Nanotubes and Hollow Spheres[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(9): 1698-1704. doi: 10.11862/CJIC.2019.198 shu

One-Step Controllable Synthesis of Silica Nanotubes and Hollow Spheres

LIU Yang ^1,2 ,
PAN Zhao-Rui ¹ ,
SHI Xiao-Ran ¹ ,
LANG Lei-Ming ^1,2,,

1.
Laboratory of Advanced Functional Materials of Nanjing, School of Environmental Science, Nanjing Xiaozhuang University, Nanjing 211171, China
2.
State Key Laboratory of Analytical Chemistry for Life Science, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Corresponding author: LANG Lei-Ming, langleiming@njxzc.edu.cn
Received Date: 22 March 2019
Revised Date: 10 June 2019

Figures(7)

A simple and facile sol-gel method was used to fabricate novel uniform silica nanotubes and hollow spheres controllably in the same reaction system. The different reaction conditions were investigated, such as reaction time, addition and stirring rate of tetraethyl orthosilicate (TEOS) and the ratio of water and ethanol, which had important influence on the formation of the silica nanotubes with uniform morphologies. The formation process investigation of silica nanotubes discloses that ammonium citrate (AC) crystals have the thin pillar-like morphologies in the mixed solution including ethanol and water, which acts as an important template for the gradual aggradation of silica colloids on their surface to form the tubular structure. The silica hollow spheres have the similar formation mechanism to that of silica nanotubes with a little difference of using citric acid (CA) as a starting structure-directing agent.
- silica nanotube,
- hollow sphere,
- citric acid,
- ammonium citrate,
- sol-gel preparation
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