Citation: WANG Ting-Wei, CHEN Xing-Han, CHEN Hong-Jin, SHAO Jun-Yan, SHI Heng, XING Jie-Ni, LÜ Guang-Yu, ZHANG Rui, LIU Jian. Synthesis, Structure and Magnetic Properties of Binuclear Pinene Pyridyl Pyrazine Dy(Ⅲ) Complex[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(7): 1183-1187. doi: 10.11862/CJIC.2019.136 shu

Synthesis, Structure and Magnetic Properties of Binuclear Pinene Pyridyl Pyrazine Dy(Ⅲ) Complex

Jiangsu Key Lab of Biomass-Based Green Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China

Corresponding author: ZHANG Rui, zhangrui@njfu.edu.cn LIU Jian, liu.jian@njfu.edu.cn
Received Date: 19 January 2019
Revised Date: 6 April 2019

Figures(6)

Single ion magnets based on Dy(Ⅲ) complexes are of particular interest due to their doubly degenerate high spin ground state and strong axial single-ion anisotropy. Herein, a new dinuclear dysprosium (Dy) complex[Dy₂(PY)(TTA)₆] (1) was prepared by the reaction between a chiral pinene pyridyl pyrazine ligand (PY) and β-diketone Dy compound (Dy(TTA)₃). X-ray single crystal diffraction characterization of the obtained complex indicated that the configuration inversion of chiral pinene group occurred during the crystal growth, which results in a central symmetry configuration. The temperature-dependent susceptibility test revealed that the prepared Dy complex exhibits slow magnetic relaxation in the absence of external dc magnetic field.
- pinene pyridyl,
- β-diketone,
- dinuclear dysprosium complex,
- magnetic property
1. [1]
  YOU Xiao-Zeng. Molecular-Based Materials:Opto-electronic Functional Compounds. Shanghai:Shanghai Science and Technology Press, 2001.
2. [2]
  Yamanouchi M, Chiba D, Matsukura F, et al. Nature, 2004, 428(6982):539-542 doi: 10.1038/nature02441
3. [3]
  Saitoh E, Miyajima H, Yamaoka T, et al. Nature, 2004, 432(7034):203-206
4. [4]
  Yang L, Li J, Pu T C, et al. Dalton Trans., 2017, 46(20):6670-6676 doi: 10.1039/C7DT00753A
5. [5]
  Wu D Q, Shao D, Wei X Q, et al. J. Am. Chem. Soc., 2017, 139(34):11714-11717 doi: 10.1021/jacs.7b07008
6. [6]
  Bogani L, Wernsdorfer W. Nat. Mater., 2008, 7(3):179-186 doi: 10.1038/nmat2133
7. [7]
  Leuenberger M N, Loss D. Nature, 2001, 410(6830):789-793 doi: 10.1038/35071024
8. [8]
  Hussain B, Savard D, Burchell T J, et al. Chem. Commun., 2009(9):1100-1102 doi: 10.1039/b818295g
9. [9]
  Liu X Q, Zhang Y, Shi W, et al. Inorg. Chem., 2018, 57(21):13409-13414 doi: 10.1021/acs.inorgchem.8b01981
10. [10]
  WANG Ting-Wei, CHEN Hong-Jin, ZHANG Rui, et al. Chinese J. Inorg. Chem., 2018, 34(6):1007-1017
11. [11]
  Ishikawa N, Sugita M, Ishikawa T, et al. J. Am. Chem. Soc., 2003, 125(29):8694-8695 doi: 10.1021/ja029629n
12. [12]
  Ge J Y, Wang H Y, Li J, et al. Dalton Trans., 2017, 46(10):3353-3362 doi: 10.1039/C7DT00298J
13. [13]
  Jiang S D, Wang B W, Su G, et al. Angew. Chem. Int., Ed., 2010, 49(41):7448-7451 doi: 10.1002/anie.v49:41
14. [14]
  Tang J, Hewitt I, Madhu N T, et al. Angew. Chem. Int. Ed., 2006, 45(11):1729-1733 doi: 10.1002/(ISSN)1521-3773
15. [15]
  Takamatsu S, Ishikawa T, Koshihara S Y, et al. Inorg. Chem., 2007, 46(18):7250-7252 doi: 10.1021/ic700954t
16. [16]
  Li D P, Wang T W, Li C H, et al. Chem. Commun., 2010, 46(17):2929-2931 doi: 10.1039/b924547b
17. [17]
  Li X L, Gao Y L, Feng X L, et al. Dalton Trans., 2012, 41(38):11829-11835 doi: 10.1039/c2dt31007d
18. [18]
  Li X L, Chen C L, GaoY L. Chem. Eur. J., 2012, 18:14632-14637 doi: 10.1002/chem.201201190
19. [19]
  SAINT-Plus, Vers. 6.02, Bruker Analytical X-ray System, Madison, WI, 1999.
20. [20]
  Sheldrick G M. SADABS, an Empirical Absorption Correction Program, Bruker Analytical X-ray Systems, Madison, WI, 1996.
21. [21]
  Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Germany, 1997.
22. [22]
  Li D P, Zhang X P, Wang T W, et al. Chem. Commun., 2011, 47(24):6867-6869 doi: 10.1039/c1cc11659b
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