Citation: WEN Hao, SHI Chang-Dong, HU Yao, RONG Hong-Ren, SHA Yan-Yong, LIU Hong-Jiang, ZHANG Han-Ping, LIU Qi. Two Dimensional Coordination Polymer Derived Nitrogen-Doped Carbon/ZnO Nanocomposites as High Performance Anode Material of Lithium-Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(1): 50-58. doi: 10.11862/CJIC.2019.015 shu

Two Dimensional Coordination Polymer Derived Nitrogen-Doped Carbon/ZnO Nanocomposites as High Performance Anode Material of Lithium-Ion Batteries

WEN Hao ¹ ,
SHI Chang-Dong ¹ ,
HU Yao ² ,
RONG Hong-Ren ¹ ,
SHA Yan-Yong ¹ ,
LIU Hong-Jiang ^2,, ,
ZHANG Han-Ping ¹ ,
LIU Qi ^1,3,,

1.
School of Petrochemical Engineering and Jiangsu Key Laboratory of Fine Petro-chemical Technology, Changzhou University, Changzhou, Jiangsu 213164, China
2.
Department of Chemistry, College of Science, Shanghai University, Shanghai 200444, China
3.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China

Corresponding author: LIU Hong-Jiang, liuqi62@163.com LIU Qi, liuhj@shu.edu.cn
Received Date: 26 July 2018
Revised Date: 8 November 2018

Figures(7)

Nitrogen-doped carbon/ZnO nanoparticles (ZnO-N-C) have been synthesized via an ordinary one-step calcination of a two-dimensional zinc-based coordination polymer[Zn(tfbdc)(4, 4'-bpy)(H₂O)₂] (H₂tfbdc=tetrafluoro-terephthalic acid, 4, 4'-bpy=4, 4'-bipyridine). As an anode material for lithium-ion batteries, the obtained ZnO-N-C electrode exhibited high reversible capacity, excellent cyclic stability and better rate capability. The reversible capacity of the ZnO-N-C electrode maintains 611 mAh·g^-1 after 50 cycles at a current density of 50 mA·g^-1.
- zinc oxide,
- nitrogen-doped carbon,
- nanoparticles,
- anode material,
- lithium-ion battery,
- coordination polymer
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沈阳化工大学材料科学与工程学院沈阳 110142