Citation: LI Yu, ZOU Xun-Zhong, ZHUANG Wen-Liu, QIU Wen-Da, GU Jin-Zhong. Syntheses, Crystal Structures and Luminescent Properties of Two Zinc(Ⅱ) Coordination Polymers Constructed from Ether-Bridged Tricarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(1): 149-154. doi: 10.11862/CJIC.2019.009 shu

Syntheses, Crystal Structures and Luminescent Properties of Two Zinc(Ⅱ) Coordination Polymers Constructed from Ether-Bridged Tricarboxylic Acid

1.
Foshan Research Center for Special Functional Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China
2.
College of chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: QIU Wen-Da, qiuwdgy@hotmail.com GU Jin-Zhong, gujzh@lzu.edu.cn
Received Date: 7 September 2018
Revised Date: 19 October 2018

Figures(7)

Two 1D zinc(Ⅱ) coordination polymers, namely[Zn(μ-Hcpta)(4, 4'-bipy)(H₂O)]_n (1) and {[Zn₃(μ₃-dbba)₂(phen)₃]·6H₂O}_n (2), have been constructed hydrothermally using two ether-bridged tricarboxylic acids:2-(4-carbo-xylphenoxy) terephthalic acid (H₃cpta) and 2-(3, 5-dicarboxylatobenzyloxy) benzoic acid(H₃dbba), 4, 4'-bipyridine (4, 4'-bipy), 1, 10-phenanthroline (phen) and zinc chloride. Single-crystal X-ray diffraction analyses revealed that two complexes crystallize in the monoclinic system, space groups P2₁ or I2. Complexes 1 and 2 show two different 1D chain structures.
- coordination polymer,
- tricarboxylic acid,
- luminescent properties
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沈阳化工大学材料科学与工程学院沈阳 110142