Citation: ZHOU Qi, LI Zhi-Yang. Preparation and Hydrogen Evolution Properties of Nanoporous Ni, Ni-Mo Alloys and Their Oxides[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(12): 2188-2196. doi: 10.11862/CJIC.2018.268 shu

Preparation and Hydrogen Evolution Properties of Nanoporous Ni, Ni-Mo Alloys and Their Oxides

ZHOU Qi ^, ,
LI Zhi-Yang

State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China

Corresponding author: ZHOU Qi, zhouxq301@sina.com
Received Date: 11 June 2018
Revised Date: 25 September 2018

Figures(10)

Nano porous Ni, Ni-Mo and their oxides electrode materials were prepared by rapid solidification and de-alloying. The phase, morphology and pore size distribution of porous electrode materials were characterized by XRD, SEM, TEM and N₂ absorption-desorption test, and the electro-catalytic hydrogen evolution of porous electrode was tested by linear scanning voltammetry, Tafel slope and chronopotentiometry. The results show that the hydrogen evolution activity of Ni-Mo alloy was the strongest and the process of hydrogen evolution is controlled by Volmer-Heyrovsky step. Its apparent exchange current density (j₀) was 0.25 mA·cm^-2. After electrolyzing 10 000 seconds at constant current density (100 mA·cm^-2), hydrogen evolution over-potential increased only by 39 mV, showing excellent hydrogen evolution stability. The improvement of specific surface area and intrinsic catalytic activity of Ni-Mo alloy electrode resulted in lower hydrogen evolution over-potential.
- rapid quenching,
- de-alloying,
- Ni-Mo alloy,
- electro-catalytic hydrogen evolution
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