Citation: CHEN Xiao-Li, CUI Hua-Li, YANG Hua, REN Yi-Xia, WANG Ji-Jiang, WANG Xiao. Syntheses, Crystal Structures and Properties of Three Metal Complexes Based on 3, 3', 4, 4'-Tetracarboxyazobenzene[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(12): 2298-2306. doi: 10.11862/CJIC.2018.266 shu

Syntheses, Crystal Structures and Properties of Three Metal Complexes Based on 3, 3', 4, 4'-Tetracarboxyazobenzene

School of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Laboratory of New Energy & New Function Materials, Yan'an University, Yan'an, Shaanxi 716000, China

Corresponding author: CHEN Xiao-Li, chenxiaoli003@163.com
Received Date: 30 August 2018
Revised Date: 14 September 2018

Figures(14)

Three transition metal complexes based on H₄ddb ligand, namely[Co₂(ddb)(phen)₂(H₂O)₆]·3H₂O (1), [Co(ddb)_0.5(bpy)_0.5(H₂O)₃]_n (2) and {[Ag(dpe)]·0.5(H₂ddb)·H₂O}_n (3). (H₄ddb=3, 3', 4, 4'-tetracarboxyazobenzene, bpy=4, 4'-pyridine, dpe=1, 2-di(4-pyridyl) ethylene) have been synthesized and structurally characterized by elemental anal-yses, IR spectroscopy, powder X-ray diffraction and single-crystal X-ray diffraction analyses. Complex 1 is binuclear structure, which is linked into 3D supramolecular network through rich hydrogen bonding interactions. Complex 2 shows 2D network constructed from Co²⁺ ion cross-linked by ddb^4- ligands via μ₄:η¹, η¹, η¹, η¹ coordina-tion mode. Complex 3 is linear chain structure based on Ag(Ⅰ) ion and dpe ligands. Interestingly, the guest molecule H₂ddb^2- extends a 3D supramolecular structure of 3 through intermolecular hydrogen bonding interactions. In addition, the thermal stabilities and luminescence properties of 1~3 were also studied.
- transition metal,
- 3, 3', 4, 4'-tetracarboxyazobenzene,
- crystal structure,
- luminescence
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