Citation: LI Yu-Qin, HU Na, ZHANG Fei, ZHU Mei-Hua, WU Ting, CHEN Xiang-Shu. Rapid Synthesis of Low-Silica Chabazite Zeolite with the Addition of Heterogenous Seeds[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(12): 2143-2152. doi: 10.11862/CJIC.2018.243 shu

Rapid Synthesis of Low-Silica Chabazite Zeolite with the Addition of Heterogenous Seeds

Institute of Advanced Materials(IAM), State-Province Joint Engineering Laboratory of Zeolite Membrane Materials, College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China

Corresponding author: CHEN Xiang-Shu, cxs66cn@jxnu.edu.cn
Received Date: 27 June 2018
Revised Date: 26 August 2018

Figures(14)

Pure-phase low-silica chabazite zeolites were rapidly synthesized by the addition of heterogenous seeds (zeolite T) without organic structural directing agents (OSDAs). Structural properties and morphology characteristics of the products were characterized using XRD, SEM, TEM, ²⁷Al MAS NMR and UV Raman spectroscopy. Crystallization process of chabazite and the various parameters such as seed content, n_Al₂O₃/n_SiO₂, n_H₂O/n_SiO₂ and alkalinity on the crystallization of crystals were investigated in detail. The formation mechanism of chabazite zeolite induced by zeolite T seed was also discussed. Only zeolite L was formed in the in-situ synthesis system while pure chabazite zeolite was fast obtained by adding a certain amount of zeolite T into the gel. The six-membered (6R) and four-membered rings (4R) released from the dissolved zeolite T under certain hydrothermal conditions rapidly formed the characteristic unit of chabazite zeolite (CHA cage), which inhibited the formation of the characteristic unit and characteristic cage of zeolite L (the CAN cage without four-membered ring).
- chabazite zeolite,
- hydrothermal synthesis,
- heterogenous seeds,
- OSDA-free
1. [1]
  Sapawe N, Jalil A A, Triwahyono S, et al. Chem. Eng. J., 2013, 229:388-398 doi: 10.1016/j.cej.2013.06.005
2. [2]
  Cui Y, Kita H, Okamoto K I. J. Mater. Chem., 2004, 14:924-932 doi: 10.1039/b311881a
3. [3]
  Zhou R F, Ping E W, Funke H H, et al. J. Membr. Sci., 2013, 444:384-393 doi: 10.1016/j.memsci.2013.05.048
4. [4]
  Zheng Y H, Hu N, Wang H M, et al. J. Membr. Sci., 2015, 475:303-310 doi: 10.1016/j.memsci.2014.10.048
5. [5]
  Breck D W. Zeolite Molecular Sieves:Structure, Chemistry, and Use. New York:John Wiley & Sons, 1974.
6. [6]
  Zhu Q J, Kondo J N, Ohnuma R, et al. Microporous Mesoporous Mater., 2008, 112:153-161 doi: 10.1016/j.micromeso.2007.09.026
7. [7]
  Smith R L, Svelle S, Campo P D, et al. Appl. Catal., A, 2015, 505:1-7 doi: 10.1016/j.apcata.2015.06.027
8. [8]
  Hasegawa Y, Abe C, Nishioka M, et al. J. Membr. Sci., 2010, 363:256-264 doi: 10.1016/j.memsci.2010.07.040
9. [9]
  Li X S, Kita H, Zhu H, et al. Microporous Mesoporous Mater., 2011, 143:270-276 doi: 10.1016/j.micromeso.2011.03.006
10. [10]
  Jiang J, Wang X R, Zhang Y T, et al. Microporous Mesoporous Mater., 2015, 215:98-108 doi: 10.1016/j.micromeso.2015.05.033
11. [11]
  Singh R K, Webley P. Adsorption, 2005, 11(S1):173-177 doi: 10.1007/s10450-005-5918-3
12. [12]
  Bourgogne M, Guth J L, Wey R. US Patent, 4503024. 1985-03-05.
13. [13]
  Nouri A, Jafari M, Kazemimoghadam M, et al. Chem. Eng. Technol., 2014, 37(2):317-324 doi: 10.1002/ceat.v37.2
14. [14]
  Ridha F N, Yang Y X, Webley P A. Microporous Mesoporous Mater., 2009, 117:497-507 doi: 10.1016/j.micromeso.2008.07.034
15. [15]
  Liu B, Zheng Y H, Hu N, et al. Microporous Mesoporous Mater., 2014, 196:270-276 doi: 10.1016/j.micromeso.2014.05.019
16. [16]
17. [17]
  Wu Z F, Song J W, Ji Y Y, et al. Chem. Mater., 2008, 20(2):357-359 doi: 10.1021/cm071648e
18. [18]
  Zhang H Y, Xie B, Meng X J, et al. Microporous Mesoporous Mater., 2013, 180:123-129 doi: 10.1016/j.micromeso.2013.06.031
19. [19]
  ZHAO Dong-Pu, ZHANG Yan, LI Zhuo, et al. Chinese J. Inorg. Chem., 2016, 32(11):1995-2002
20. [20]
  CHEN Yan-Hong, CUI Hong-Xia, HAN Dong-Min, et al. Chinese J. Inorg. Chem., 2018, 34(3):461-466
21. [21]
  Majano G, Darwiche A, Mintova S, et al. Ind. Eng. Chem. Res., 2009, 48(15):7084-7091 doi: 10.1021/ie8017252
22. [22]
  Zhong S L, Song S C, Wang B, et al. Microporous Mesoporous Mater., 2018, 263:11-20 doi: 10.1016/j.micromeso.2017.11.034
23. [23]
  Zhou R F, Li Y Q, Liu B, et al. Microporous Mesoporous Mater., 2013, 179:128-135 doi: 10.1016/j.micromeso.2013.06.003
24. [24]
  ZHOU Rong-Fei, LIN Xiao, XU Nan-Ping. Acta Petrolei Sinica:Petroleum Processing Section, 2005, 21(6):19-24
25. [25]
  Treacy M M J, Higgins J B. Collection of Simulated XRD Powder Patterns for Aeolites. Amsterdam:Elsevier, 2001:9
26. [26]
  CHEN Li. Thesis for the Doctorate of East China Normal University. 2010.
27. [27]
  ZHANG Hai-Yan. Thesis for the Doctorate of Jilin University. 2013.
28. [28]
  Gonthier S, Thompson R W. Stud. Surf. Sci. Catal., 1994, 85:43-73 doi: 10.1016/S0167-2991(08)60764-8
29. [29]
  Flanigen E M. Adv. Chem. Ser., 1973, 121:119-139 doi: 10.1021/advances
30. [30]
  Suzuki Y, Wakihara T, Itabashi K, et al. Top. Catal., 2009, 52:67-74 doi: 10.1007/s11244-008-9136-6
31. [31]
  Imai H, Hayashida N, Yokoi T, et al. Microporous Mesoporous Mater., 2014, 196:341-348 doi: 10.1016/j.micromeso.2014.05.043
32. [32]
  Knops-Gerrits P P, De Vos D E, Feijen E J P, et al. Microporous Mater., 1997, 8:3-17 doi: 10.1016/S0927-6513(96)00088-0
33. [33]
  Yu Y, Xiong G, Li C, et al. Microporous Mesoporous Mater., 2001, 46:23-34 doi: 10.1016/S1387-1811(01)00271-2
34. [34]
  Angell C L. J. Phys. Chem., 1973, 77(2):222-227 doi: 10.1021/j100621a015
35. [35]
  Kamimura Y, Itabashi K, Okubo T. Microporous Mesoporous Mater., 2012, 147(1):149-156 doi: 10.1016/j.micromeso.2011.05.038
36. [36]
  Kamimura Y, Tanahashi S, Itabashi K, et al. J. Phys. Chem. C, 2011, 115:744-750 doi: 10.1021/jp1098975
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