Citation: HU Bo, GAO Lin, QIAO Yu, CHE Guang-Bo. Synthesis of Fluorescent Molecularly Imprinted Polymers Based on Europium(Ⅲ) Complex for Selective Determination of Trace 2, 4, 6-Trichlorophenol[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(8): 1531-1537. doi: 10.11862/CJIC.2018.169 shu

Synthesis of Fluorescent Molecularly Imprinted Polymers Based on Europium(Ⅲ) Complex for Selective Determination of Trace 2, 4, 6-Trichlorophenol

HU Bo ^1,3 ,
GAO Lin ^1,3 ,
QIAO Yu ^1,2 ,
CHE Guang-Bo ^1,,

1.
Key Laboratory of Preparation and Applications of Environmental Friendly Materials(Ministry of Education), Jilin Normal University, Changchun 130103, China
2.
College of Chemistry, Jilin Normal University, Siping, Jilin 136000, China
3.
College of Environmental Science and Engineering, Jilin Normal University, Siping, Jilin 136000, China

Corresponding author: CHE Guang-Bo, cgbpapper@163.com
Received Date: 5 March 2018
Revised Date: 18 April 2018

Figures(7)

Fluorescent molecularly imprinted polymers(FMIPs) for selective determination 2, 4, 6-trichlorophenol were devised and fabricated. Here, europium(Ⅲ) complexes were used as fluorescence detection tool via the fluorescence quenching with templates. The FMIPs have a linear fluorescent response in 0~70 nmol·L^-1 concentration range, and the correlation coefficient was 0.996 28. The FMIPs exhibit excellent sensitivity with the limit of detection of 3.12 nmol·L^-1. In addition, FMIPs show good thermal stability and appreciable selectivity over several analogues. The experimental results showed that FMIPs could be used for selective fluorescence detection of low concentrations of chlorophenols.
- europium complex,
- fluorescence detection,
- molecularly imprinted polymer,
- 2, 4, 6-trichlorophenol
1. [1]
  Czaplicka M. Sci. Total Environ., 2004, 322(1/2/3):21-39
2. [2]
  Igbinosa E O, Odjadjare E E, Chigor V N, et al. The Sci. World J., 2013, 3:75-84
3. [3]
  Guo J Q, Wu C H, Lv S L, et al. Environ. Pollut., 2016, 214:478-484 doi: 10.1016/j.envpol.2016.04.074
4. [4]
  Patterson A T, Kaffenberger B H, Keller R A, et al. J. Am. Acad. Dermatol., 2016, 74(1):143-170 doi: 10.1016/j.jaad.2015.05.006
5. [5]
  Olaniran A O, Igbinosa E O. Chemosphere, 2011, 83(10):1297-1306 doi: 10.1016/j.chemosphere.2011.04.009
6. [6]
  Arora P K, Bae H. Microb. Cell Fact., 2014, 13(1):1-17 doi: 10.1186/1475-2859-13-1
7. [7]
  Bolobajev J, Trapido M, Goi A. Appl. Catal. B, 2016, 187:75-82 doi: 10.1016/j.apcatb.2016.01.015
8. [8]
  Vandergrift G W, Krogh E T, Gill C G. Anal. Chem., 2017, 89(10):5629-5636 doi: 10.1021/acs.analchem.7b00908
9. [9]
  Olu-Owolabi B I, Alabi A H, Diagboya P N, et al. J. Environ. Manage., 2017, 192:94-99 doi: 10.1016/j.jenvman.2017.01.055
10. [10]
  Zhou Y, Zhang J F, Yoon J. Chem. Rev., 2014, 114(10):5511-5571 doi: 10.1021/cr400352m
11. [11]
  Chinen A B, Guan C M, Ferrer J R, et al. Chem. Rev., 2015, 115(19):10530-10574 doi: 10.1021/acs.chemrev.5b00321
12. [12]
  Hudson N, Baker A, Reynolds D. River Res. Appl., 2010, 23(6):631-649
13. [13]
  Liang L L, Lan F F, Ge S G, et al. Anal. Chem., 2017, 89(6):3597-3605 doi: 10.1021/acs.analchem.6b04978
14. [14]
  Nsibande S A, Forbes P B. Anal. Chim. Acta, 2016, 945:9-22 doi: 10.1016/j.aca.2016.10.002
15. [15]
  Choi M G, Lee S H, Jung Y U, et al. Sens. Actuators B, 2017, 251:713-719 doi: 10.1016/j.snb.2017.05.098
16. [16]
  Xu L, Zhou W H, Liu J W. Anal. Chim. Acta, 2017, 977:44-51 doi: 10.1016/j.aca.2017.04.046
17. [17]
  Edelmann F T. Coord. Chem. Rev., 2017, 338:27-140 doi: 10.1016/j.ccr.2017.02.001
18. [18]
  MAO Lan-Lan, ZHANG Li-Ming, DENG Yan, et al. Chinese J. Inorg. Chem., 2016, 32(12):2095-2101
19. [19]
  Campos-Gonalves I, Costa B F O, Santos R F, et al. Mater. Des., 2017, 130:263-274 doi: 10.1016/j.matdes.2017.05.064
20. [20]
  Babailov S P. Sens. Actuators B, 2017, 251:108-111 doi: 10.1016/j.snb.2017.05.033
21. [21]
  Dochai S, Vetica F, Puttreddy R, et al. Angew. Chem. Int. Ed., 2016, 55(52):16153-16155 doi: 10.1002/anie.201610196
22. [22]
  MAO Yan-Li, LUO Shi-Tian, WU Jun-Feng, et al. Chinese J. Inorg. Chem., 2017, 33(1):81-88 doi: 10.11862/CJIC.2017.007
23. [23]
  Yoshikawa M, Tharpa K, Dima S O. Chem. Rev., 2016, 116(19):11500-11528 doi: 10.1021/acs.chemrev.6b00098
24. [24]
  Medlock J, Das A A K, Madden L A, et al. Chem. Soc. Rev., 2017, 46(16):5110-5127 doi: 10.1039/C7CS00179G
25. [25]
  Ashley J, Shahbazi M A, Kant K, et al. Biosens. Bioelectron., 2017, 91:606-615 doi: 10.1016/j.bios.2017.01.018
26. [26]
  Ansari S, Karimi M. Anal. Chem., 2017, 89:146-162
27. [27]
  Zhou Z P, Li T, Xu W Z, et al. Sens. Actuators B, 2017, 240:1114-1122 doi: 10.1016/j.snb.2016.09.092
28. [28]
  Yu J L, Wang X Y, Kang Q, et al. Environ. Sci-Nano, 2016, 4(2):493-502
29. [29]
  Yang J, Lin Z Z, Zhong H P, et al. Sens. Actuators B, 2017, 252:561-567 doi: 10.1016/j.snb.2017.06.042
30. [30]
  Bortoluzzi M, Reolon A, Castro J, et al. RSC Adv., 2016, 6(39):32727-32739 doi: 10.1039/C6RA01741J
1. [1]
  Xiaofei NIU , Ke WANG , Fengyan SONG , Shuyan YU . Self-assembly of [Pd₆(L)₄]⁸⁺-type macrocyclic complexes for fluorescent sensing of HSO₃^-. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1233-1242. doi: 10.11862/CJIC.20240057
2. [2]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
3. [3]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
4. [4]
  Yingying Yan , Wanhe Jia , Rui Cai , Chun Liu . An AIPE-active fluorinated cationic Pt(Ⅱ) complex for efficient detection of picric acid in aqueous media. Chinese Chemical Letters, 2024, 35(5): 108819-. doi: 10.1016/j.cclet.2023.108819
5. [5]
  Tiankai Sun , Hui Min , Zongsu Han , Liang Wang , Peng Cheng , Wei Shi . Rapid detection of nanoplastic particles by a luminescent Tb-based coordination polymer. Chinese Chemical Letters, 2024, 35(5): 108718-. doi: 10.1016/j.cclet.2023.108718
6. [6]
  Zhiqiang Liu , Qiang Gao , Wei Shen , Meifeng Xu , Yunxin Li , Weilin Hou , Hai-Wei Shi , Yaozuo Yuan , Erwin Adams , Hian Kee Lee , Sheng Tang . Removal and fluorescence detection of antibiotics from wastewater by layered double oxides/metal-organic frameworks with different topological configurations. Chinese Chemical Letters, 2024, 35(8): 109338-. doi: 10.1016/j.cclet.2023.109338
7. [7]
  Jia-Li Xie , Tian-Jin Xie , Yu-Jie Luo , Kai Mao , Cheng-Zhi Huang , Yuan-Fang Li , Shu-Jun Zhen . Octopus-like DNA nanostructure coupled with graphene oxide enhanced fluorescence anisotropy for hepatitis B virus DNA detection. Chinese Chemical Letters, 2024, 35(6): 109137-. doi: 10.1016/j.cclet.2023.109137
8. [8]
  Kangmin Wang , Liqiu Wan , Jingyu Wang , Chunlin Zhou , Ke Yang , Liang Zhou , Bijin Li . Multifunctional 2-(2′-hydroxyphenyl)benzoxazoles: Ready synthesis, mechanochromism, fluorescence imaging, and OLEDs. Chinese Chemical Letters, 2024, 35(10): 109554-. doi: 10.1016/j.cclet.2024.109554
9. [9]
  Gengchen Guo , Tianyu Zhao , Ruichang Sun , Mingzhe Song , Hongyu Liu , Sen Wang , Jingwen Li , Jingbin Zeng . Au-Fe₃O₄ dumbbell-like nanoparticles based lateral flow immunoassay for colorimetric and photothermal dual-mode detection of SARS-CoV-2 spike protein. Chinese Chemical Letters, 2024, 35(6): 109198-. doi: 10.1016/j.cclet.2023.109198
10. [10]
  Dong-Xue Jiao , Hui-Li Zhang , Chao He , Si-Yu Chen , Ke Wang , Xiao-Han Zhang , Li Wei , Qi Wei . Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units. Chinese Journal of Structural Chemistry, 2024, 43(6): 100304-100304. doi: 10.1016/j.cjsc.2024.100304
11. [11]
  Jia-Mei Qin , Xue Li , Wei Lang , Fu-Hao Zhang , Qian-Yong Cao . An AIEgen nano-assembly for simultaneous detection of ATP and H₂S. Chinese Chemical Letters, 2024, 35(6): 108925-. doi: 10.1016/j.cclet.2023.108925
12. [12]
  Yunxin Li , Jinghui Zhang , Jisen Chen , Feng Zhu , Zhiqiang Liu , Peng Bao , Wei Shen , Sheng Tang . Detection of SARS-CoV-2 based on artificial intelligence-assisted smartphone: A review. Chinese Chemical Letters, 2024, 35(7): 109220-. doi: 10.1016/j.cclet.2023.109220
13. [13]
  Ting-Ting Huang , Jin-Fa Chen , Juan Liu , Tai-Bao Wei , Hong Yao , Bingbing Shi , Qi Lin . A novel fused bi-macrocyclic host for sensitive detection of Cr₂O₇²⁻ based on enrichment effect. Chinese Chemical Letters, 2024, 35(7): 109281-. doi: 10.1016/j.cclet.2023.109281
14. [14]
  Jia Chen , Yun Liu , Zerong Long , Yan Li , Hongdeng Qiu . Colorimetric detection of α-glucosidase activity using Ni-CeO₂ nanorods and its application to potential natural inhibitor screening. Chinese Chemical Letters, 2024, 35(9): 109463-. doi: 10.1016/j.cclet.2023.109463
15. [15]
  Hualei Xu , Manman Han , Haiqiang Liu , Liang Qin , Lulu Chen , Hao Hu , Ran Wu , Chenyu Yang , Hua Guo , Jinrong Li , Jinxiang Fu , Qichen Hao , Yijun Zhou , Jinchao Feng , Xiaodong Wang . 4-Nitrocatechol as a novel matrix for low-molecular-weight compounds in situ detection and imaging in biological tissues by MALDI-MSI. Chinese Chemical Letters, 2024, 35(6): 109095-. doi: 10.1016/j.cclet.2023.109095
16. [16]
  Ke-Ai Zhou , Lian Huang , Xing-Ping Fu , Li-Ling Zhang , Yu-Ling Wang , Qing-Yan Liu . Fluorinated metal-organic framework for methane purification from a ternary CH4/C2H6/C3H8 mixture. Chinese Journal of Structural Chemistry, 2023, 42(11): 100172-100172. doi: 10.1016/j.cjsc.2023.100172
17. [17]
  Simin Wei , Yaqing Yang , Junjie Li , Jialin Wang , Jinlu Tang , Ningning Wang , Zhaohui Li . The Mn/Yb/Er triple-doped CeO₂ nanozyme with enhanced oxidase-like activity for highly sensitive ratiometric detection of nitrite. Chinese Chemical Letters, 2024, 35(6): 109114-. doi: 10.1016/j.cclet.2023.109114
18. [18]
  Chao Ma , Cong Lin , Jian Li . MicroED as a powerful technique for the structure determination of complex porous materials. Chinese Journal of Structural Chemistry, 2024, 43(3): 100209-100209. doi: 10.1016/j.cjsc.2023.100209
19. [19]
  Mengjuan Sun , Muye Zhou , Yifang Xiao , Hailei Tang , Jinhua Chen , Ruitao Zhang , Chunjiayu Li , Qi Ya , Qian Chen , Jiasheng Tu , Qiyue Wang , Chunmeng Sun . Reversibly size-switchable polyion complex micelles for antiangiogenic cancer therapy. Chinese Chemical Letters, 2024, 35(7): 109110-. doi: 10.1016/j.cclet.2023.109110
20. [20]
  Yuanjin Chen , Xianghui Shi , Dajiang Huang , Junnian Wei , Zhenfeng Xi . Synthesis and reactivity of cobalt dinitrogen complex supported by nonsymmetrical pincer ligand. Chinese Chemical Letters, 2024, 35(7): 109292-. doi: 10.1016/j.cclet.2023.109292

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(1415)
HTML views(68)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142