Citation: YAN Shi-Cheng, WU Da-Ling, ZHANG Min-Zhi, GUAN Quan-Yin, ZHAO Guo-Liang. Three Cd(Ⅱ) and Zn(Ⅱ) Coordination Polymers Based on 2-(4'-Carboxyphenyl)-1H-imidazole-4, 5-dicarboxylic Acid: Syntheses, Topological Structures, Fluorescent Spectra and DNA Binding[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(6): 1110-1120. doi: 10.11862/CJIC.2018.149 shu

Three Cd(Ⅱ) and Zn(Ⅱ) Coordination Polymers Based on 2-(4'-Carboxyphenyl)-1H-imidazole-4, 5-dicarboxylic Acid: Syntheses, Topological Structures, Fluorescent Spectra and DNA Binding

1.
Xingzhi College, Zhejiang Normal University, Jinhua, Zhejiang 321004, China
2.
College of Chemistry and Life Science, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: ZHAO Guo-Liang, sky53@zjnu.cn
Received Date: 17 September 2017
Revised Date: 26 April 2018

Figures(6)

Three coordination polymers of cadmium and zinc {[Cd₂(CPhIDC)(bimb)]·H₂O}_n (1), {[Cd₂(CPhIDC)(phen)₂]·3H₂O}_n (2), {[Zn₂(CPhIDC)(bpp)]·1.5H₂O}_n (3), (H₄CPhIDC=2-(4'-carboxyphenyl)-1H-imidazole-4, 5-dicar-boxylic acid, bimb=1, 4-bis(imidazoL-1-yl)butane, phen=1, 10-phenanthroline, bpp=1, 3-di(pyridin-4-yl)propane) have been synthesized by solvothermal reaction and characterized by IR, EA and PXRD. Single crystal X-ray diffraction shows that the H₄CPhIDC ligand presents fully deprotonated motifs of CPhIDC^4- in three corresponding polymers. Moreover, the fully deprotonated ligands coordinate in the μ₄ and μ₅ manner to generate 2D and 3D polymers, displaying three different coordination modes. Complexes 1 and 3 exhibit 3D structures with (3, 4, 5)-connected frameworks with (5·6·7)(4·5²·6·7²)(4·5²·6·7⁴·8²) topology, but the metal ions and auxiliary ligands are different. 2 displays a 2D wave-like fishing nets structure with 4⁴·6² topology. The fluorescence spectra in the solid state and DNA binding properties of the polymers and ligand are investigated.
- 2-(4'-carboxyphenyl)-1H-imidazole-4, 5-dicarboxylic acid,
- Cd and Zn coordination polymers,
- topological structure,
- fluorescence spectra,
- DNA binding
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沈阳化工大学材料科学与工程学院沈阳 110142