Citation: WU Da-Ling, ZHANG Min-Zhi, WU Xiao-Yong, ZHAO Guo-Liang. Syntheses, Crystal Structures and DNA-Binding of Two Zinc(Ⅱ) Complexes Constructed by 4-Methyl-1, 2, 3-thiadiazol-5-carboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(5): 973-980. doi: 10.11862/CJIC.2018.107 shu

Syntheses, Crystal Structures and DNA-Binding of Two Zinc(Ⅱ) Complexes Constructed by 4-Methyl-1, 2, 3-thiadiazol-5-carboxylic Acid

1.
College of Chemistry and Life Science, Zhejiang Normal University, Jinhua, Zhejiang 321004, China
2.
Xingzhi College, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: ZHAO Guo-Liang, sky53@zjnu.cn
Received Date: 20 November 2017
Revised Date: 11 January 2018

Figures(9)

Two new zinc complexes[Zn(MTC)₂(bpp)]_n (1) and[Zn(MTC)(phen)(H₂O)₂](MTC) (2) (HMTC=4-methyl-1, 2, 3-thiadiazol-5-carboxylic, C₄H₄N₂O₂S; bpp=1, 3-bis(4-pyridyl) propane; phen=1-10-phenanthroline) have been synthesized and characterized by single crystal X-ray diffraction, elemental analysis, IR spectra, PXRD and TG. The single crystal X-ray diffraction reveals that the complex 1 is two-dimensional network structure and crystallized in monoclinic with space group P2₁/c. Central Zn²⁺ is four-coordinated forming a distorted tetrahedron coordina-tion geometry. The complex 2 is two-dimensional layered structure and crystallized in triclinic with space group P1. Central Zn²⁺ is five-coordinated forming a distorted trigonal bipyramid coordination geometry. In addition, the interaction of complexes and ligand with EB-DNA were also studied by EtBr fluorescence probe. The interaction of complexes with DNA is stronger than ligand.
- 4-methyl-1, 2, 3-thiadiazol-5-carboxylic acid,
- zinc complex,
- crystal structure,
- DNA-binding
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沈阳化工大学材料科学与工程学院沈阳 110142