Citation: CAI Xue-Yu, ZHANG Qi-Long. Hg(Ⅱ) Coordination Polymers Based on trans-Bis(β-diketone)cyclohexanediimine Ligands: Syntheses and Crystal Structures[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(4): 633-638. doi: 10.11862/CJIC.2018.090 shu

Hg(Ⅱ) Coordination Polymers Based on trans-Bis(β-diketone)cyclohexanediimine Ligands: Syntheses and Crystal Structures

CAI Xue-Yu ¹ ,
ZHANG Qi-Long ^2,,

1.
School of Clinical Laboratory Science, Guizhou Medical University, Guiyang 550004, China
2.
Department of Chemistry, School of Basic Medical Sciences, Guizhou Medical University, Guiyang 550004, China

Corresponding author: ZHANG Qi-Long, gzuqlzhang@126.com
Received Date: 20 September 2017
Revised Date: 2 January 2018

Figures(7)

Four mercury(Ⅱ) complexes, namely[Hg₂(L1)Cl₄]_n (1), {[Hg₂(L2)Cl₄]·L2}_n (2), [Hg₂(L1)I₄]_n (3) and[Hg₂(L2)I₄]_n (4), have been obtained by the reaction of mercury salts with two bis(β-diketone) Schiff bases (L1=trans-bis(acetylacetone)-1, 4-diaminocyclohexane, and L2=trans-bis(benzoylacetone)-1, 4-diaminocyclohexane) in the ethanol solution. The structures of these complexes were characterized by elemental analysis, infrared spectroscopy, powder X-ray diffraction and X-ray single-crystal diffraction. In the solid state, the center Hg(Ⅱ) ions connect with γ-C atoms and three Cl-ions to form a one-dimensional chain in complexes 1, 2. In complex 3 the center Hg(Ⅱ) ions connect with O atoms and three I^- ions to form a two-dimensional net structure, while in complex 4 the center Hg(Ⅱ) ions connect with O atoms and three I-ions to form a one-dimensional chain.
- β-diketone,
- Schiff base,
- Hg(Ⅱ) coordination polymers,
- crystal structure
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