Citation: MAO Pan-Dong, WU Wei-Na, YANG Miao, YANG Qing-Wen, WANG Yuan. Li(Ⅰ)/Na(Ⅰ) Complexes and Perchlorate Salt of 2-(5-Chloroquinolin-8-yloxy)-1-(pyrrolidin-1-yl)ethanone: Syntheses, Crystal Structures and Fluorescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(3): 534-538. doi: 10.11862/CJIC.2018.087 shu

Li(Ⅰ)/Na(Ⅰ) Complexes and Perchlorate Salt of 2-(5-Chloroquinolin-8-yloxy)-1-(pyrrolidin-1-yl)ethanone: Syntheses, Crystal Structures and Fluorescence Properties

College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo, Henan 454000, China

Corresponding author: WU Wei-Na, wuwn08@hpu.edu.cn WANG Yuan, wangyuan08@hpu.edu.cn
Received Date: 11 September 2017
Revised Date: 28 December 2017

Figures(3)

Two complexes, [Li(L)₂]ClO₄ (1) and[Na(L)₂]ClO₄ (2) based on L (L=2-(5-chloroquinolin-8-yloxy)-1-(pyrrolidin-1-yl)ethanone) were synthesized and characterized by the X-ray diffraction analyses. The results show that complex 1 was isostructural with 2. The metal ion in each complex with a distorted octahedron geometry is surrounded by two acetamide ligands with N₂O₄ donor set. In addition, the structure of the perchlorate salt of L, namely (HL)ClO₄·H₂O was demonstrated. The fluorescence properties of all compounds have been investigated in detail.
- main-group metal complexes,
- amide type ligand,
- quinoline,
- crystal structure,
- fluorescence
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