Citation: ZHU Hong-Yu, YANG Han-Pei, SUN Hui-Hua, GAO Zhao, MAO Jing-Tao, WU Jun-Ming. Highly Uniform Monolayer-Carbon Nanocages: Facile Synthesis, Simple Modification and Adsorptive Properties for Aqueous Crystal Violet[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(3): 445-453. doi: 10.11862/CJIC.2018.047 shu

Highly Uniform Monolayer-Carbon Nanocages: Facile Synthesis, Simple Modification and Adsorptive Properties for Aqueous Crystal Violet

Key Laboratory of Integrated Regulation and Resource Development on Shallow Lakes, Ministry of Education, College of Environment, Hohai University, Nanjing 210098, China

Corresponding author: YANG Han-Pei, yanghanpei@hhu.edu.cn
Received Date: 23 August 2017
Revised Date: 12 December 2017

Figures(12)

Three-dimensional structures of monolayer and hollow carbon nanocages were obtained by a facile method. These nanocages with controlled wall thickness are synthesized by catalytic templating on magnesium oxides (MgO), nucleating in situ during annealing of basic magnesium carbonate, using absolute ethyl alcohol as an inexpensive precursor of carbon, and following the MgO dissolution by dilute nitric acid solution. The obtained CNCs show a specific surface area as high as 906 m²·g^-1, and conduct an adsorption capacity of 542.6 mg·g^-1 for aqueous crystal violet under experimental conditions. The hydrophilia of as-prepared CNCs can be significantly improved through a simple modification by treating CNCs with sodium dodecyl benzene sulfonate, and the hydrophilic CNCs can capture CV molecules with an adsorption capacity saturated in 748.4 mg·g^-1. The pristine and modified CNCs were extensively characterized by XRD, FT-IR, TEM, XPS and BET surface measurement, and the structure-performance of CNCs is careful correlated. The chemical adsorption mechanism during the removal of CV by CNCs is identified, and the interactions between CV and CNCs, through π-π and electrovalent bonds are proposed.
- carbon nanocages,
- surface modification,
- sodium dodecyl benzene sulfonate,
- crystal violet,
- adsorption
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