Citation: LIU Jian, ZHANG Xiao-Peng, LI Cheng-Hui. Syntheses and Ferroelectric Properties of a Couple of Chiral Europium(Ⅲ) Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(11): 2060-2064. doi: 10.11862/CJIC.2017.256 shu

Syntheses and Ferroelectric Properties of a Couple of Chiral Europium(Ⅲ) Complexes

1.
Jiangsu Key Lab of Biomass-based Green Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China
2.
Collaborative Innovation Center of Advanced Microstructures, State Key laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China
3.
Key Laboratory of Water Pollution Treatment & Resource Reuse of Hainan Province, College of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, China

Corresponding author: LIU Jian, liu.jian@nju.edu.cn
Received Date: 20 September 2017
Revised Date: 16 October 2017

Figures(4)

A couple of pinene-containing europium(Ⅲ) complexes, Eu(TTA)₃L_1a (1a) and Eu(TTA)₃L_1b (1b) (TTA=thenoyltrifluoroacetonate, L_1a=(+)-4, 5-bis(pinene)-2, 2'-bipyridine, L_1b=(-)-4, 5-bis(pinene)-2, 2'-bipyridine), were prepared and characterized. The chiral characterization was confirmed by single crystal X-ray diffraction and distinct electronic circular dichroism (CD) signals. Complex 1a crystallizes in the polar space group P1, and a strongly distorted square-antiprism environment around the Eu(Ⅲ) ion is exhibited. Due to the non-centrosymmetric structure, distinct ferroelectric behavior of complex 1a was observed as expected.
- coordination chemistry,
- chiral europium(Ⅲ) complexes,
- crystal structure,
- ferroelectric properties
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1.
沈阳化工大学材料科学与工程学院沈阳 110142